The
present study reports a novel hay biochar functionalized with
dairy effluent for enhanced tetracycline (TC) adsorption in the aqueous
phase for the first time. The enrichment of hay (i.e., alfalfa) with
dairy effluent led to significant accumulation of cationic metals
during biochar production. The dairy effluent-functionalized alfalfa
biochar (DEAF-BC) possessed strong crystallization (i.e., CaCO
3
), functional groups (i.e., CO
3
2–
, C–O stretching), and
high surface area (334 m
2
/g) related to TC adsorption.
Therefore, DEAF-BC showed higher TC adsorption capacity (835.7 mg/g)
than that of the alfalfa biochar (94.5 mg/g). The adsorption isotherm
and kinetic results for the DEAF-BC were correlated with the Freundlich,
pseudo-second-order, and intraparticle diffusion models for TC. For
the TC adsorption onto DEAF-BC, the thermodynamic analysis implied
a spontaneous and endothermic process. Possible mechanisms would include
metal complexation, hydrogen bonding, van der Waals forces, and π–π
interaction.