Sorption of 17α-Ethinylestradiol by Surfactant-Modified Zeolite-Rich Tuff from Aqueous Solutions

Dávila-Estrada, M.; Ramírez-García, J. J.; Díaz-Nava, M. C.; Solache‐Ríos, M.

doi:10.1007/s11270-016-2850-y

Cited by 12 publications

(1 citation statement)

References 39 publications

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“…Adsorption is widely employed to remove emerging pollutants in wastewater treatment. It is the most efficient method in terms of simplicity, the cost of design and operation, and insensitivity of toxic substances [10,11]. Several adsorbents have been developed and tested to remove CBZ from wastewater matrices (i.e., zeolite) [12,13].…”

Section: Introductionmentioning

confidence: 99%

Removal of Carbamazepine onto Modified Zeolitic Tuff in Different Water Matrices: Batch and Continuous Flow Experiments

Al‐Mashaqbeh

Alsafadi

Alsalhi

et al. 2021

Water

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Carbamazepine (CBZ) is the most frequently detected pharmaceutical residues in aquatic environments effluent by wastewater treatment plants. Batch and column experiments were conducted to evaluate the removal of CBZ from ultra-pure water and wastewater treatment plant (WWTP) effluent using raw zeolitic tuff (RZT) and surfactant modified zeolite (SMZ). Point zero net charge (pHpzc), X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier Transform Infrared (FTIR) were investigated for adsorbents to evaluate the physiochemical changes resulted from the modification process using Hexadecyltrimethylammonium bromide (HDTMA-Br). XRD and FTIR showed that the surfactant modification of RZT has created an amorphous surface with new alkyl groups on the surface. The pHpzc was determined to be approximately 7.9 for RZT and SMZ. The results indicated that the CBZ uptake by SMZ is higher than RZT in all sorption tests (>8 fold). Batch results showed that the sorption capacity of RZT and SMZ in WWTP effluent (0.029 and 0.25 mg/g) is higher than RZT and SMZ (0.018 and 0.14 mg/g) in ultrapure water (1.6–1.8 fold). Batch tests showed that the equilibrium time of CBZ removal in the WWTP matrix (47 h) is much longer than CBZ removal in ultrapure water. The sorption capacity of RZT & SMZ in WWTP effluent (0.03, 0.33 mg/g) is higher than RZT and SMZ (0.02 and 0.17 mg/g) in ultrapure water (1.5–2 fold) using column test. This study has clearly demonstrated that the performance of RZT and SMZ is more efficient for the removal of CBZ from realistic wastewater than ultrapure water. It is evident that the surfactant modification of RZT has enhanced the CBZ removal in both matrices.

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