Polyacrylamide titanium tungstosilicate (PAM/TiWSi) composite was synthesised using a sol–gel process and characterized via FT-IR, SEM, XRD, and TGA methods. The effects of several factors on the adsorption of Cs+, Eu3+, Ce3+and Zr4+ have been studied, including contact duration, pH, temperature, and starting concentration. PAM/TiWSi sorption of Cs+, Eu3+, Ce3+and Zr4+ was studied in terms of isotherms and kinetics. The Freundlich model was better linked with isotherm data than the Langmuir model. Cs+, Eu3+, Ce3+and Zr4+ have maximum sorption capacities (Qmax) of 30.7, 26.6, 25,3 and 29.7 mg.g−1, respectively. Furthermore, the sorption process was found based on pseudo-second-order.