The scope of the present series of papers embraces a limited portion of the field of soft rubber vulcanization, namely, vulcanization with tetramethylthiuram disulfide (TMTD) in the absence of added sulfur. However, for perspective, it has seemed desirable to include a minimum of work on simple sulfur vulcanization in the presence of accelerators. Our reason for investigating the thiuram disulfide type of cure stems from the relatively simple structure and behavior of the TMTD molecule as compared to the eight-membered-ring sulfur molecule. Thus, the reaction products, including those of macromolecular weight which occur in TMTD vulcanizates might be fewer in number and simpler in structure than those occurring in accelerated sulfur vulcanizates.The techniques which we have applied include short path distillation and radiosulfur tracer chemistry. Certain applications of these will be described in the succeeding papers. The small-scale compounding methods described by Garveys and modified to suit our purposes were used. Certain of the compounding features of our study were chosen to be reported in this introductory paper.
MaterialsOne of the main purposes of the study was to isolate and identify the vulcanization products. Therefore, more than usual care was taken in selecting and characterizing those starting materials which sometimes are of uncertain composition.Rubber. Preliminary experiments were conducted with crepe because of its recognized quality. Acetone-extracted crepe was chosen for later experiments mainly because of its low fatty acid content. The stability in air of this material was believed sufficient.Sulfur. This element, according to Nier20 contains 95% S32, 0.74% S33, 4.2% Sa4, and 0.016% S3'j. The radioactive sulfur, S*, used contained S35 as a tracer.It was obtained on allocation from the Isotope Division, U. S. Atomic Energy Commission at Oak Ridge, Tennessee. P32 was removed from the sample by 709 The half life of this isotope is 87 * 1 days.