Some less usual properties of tetracyano complexes

Combinations of natural and synthetic inclusion compounds and their thermal stability

“…The metallic ions affect very strongly their thermal stability [24,59,[65][66][67][68][69][70]. But equally the basis B, the kind of the guest G, and their numbers present in the general formula M(B)mM(CN)a'nG are decisive for the temperature interval, when the guest is liberated or when the host structure is starting its destruction.…”

“…The temperature, where the guest is lost, is determinative for the guest G or basis B substitution possibility. The results were checked by gas chromatographic experiments [67][68][69]. Also the combinations, prepared from the tetracyano complexes M(B)mM'(CN)4.nG containing various basis as dioxane, pyridine [59,66,68] and also together with CT zeolite [14,18] were effective in gas chromatography [14,70].…”

“…Cyano complexes are a well-known type of inclusion compounds [24,59,[65][66][67][68][69]. The metallic ions affect very strongly their thermal stability [24,59,[65][66][67][68][69][70].…”