Some features of induced liquid-phase bromination of aromatic compounds in the system alkali metal bromides-hydrogen peroxide

Sadygov, O. A.; Alimardanov, Kh. M.; Chalabiev, Ch. A.

doi:10.1134/s0965544106020113

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2022

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“…Hydrogen peroxide has been successfully used to oxidatively brominate (di)ketones, [44,50] arenes, both through electrophilic ring bromination [35– 39,41b,45,48–,50d,51] and radical side‐chain bromination, [36,52] heteroarenes, [40,51b] and unsaturated bonds [28a,46,49– 50d,53] …”

Section: Peroxidesmentioning

confidence: 99%

Bromide Oxidation: A Safe Strategy for Electrophilic Brominations

2022

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Bromination of organic substances is still an important reaction in modern synthetic chemistry. In view of the increasing demand for sustainable synthetic chemistry, oxidative bromination can play an important role to avoid the use of hazardous molecular bromine (Br 2 ). In this review, a complete overview of the chemical oxidants will be provided which have been used for the electrophilic as well as radical brominations, starting from less hazardous bromide Br(À I); e. g., HBr or a bromide salt, with a focus on the differences caused by the choice of oxidant.

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