The results of a transmission electron microscope study of the hydrothermal alteration products formed by perovskite and two titantate-based "synroc" formulations are reported. It was found that perovskite, the host phase for strontium-90, dissolved at combined temperatures and pressures greater than 110°C and 180 @a. Dissolution of perovskite was accompanied by an epitaxial crystallization of the titanium dioxide polymorphs, brookite and anatase. Hollandite, which incorporates cesium-137, dissolved more slowly than perovskite, with only minor TiOz crystallization. Intergrowths of zirconolite and zirkelite, the principal actinide-containing phases, were highly resistant to hydrothermal treatments, maintaining their integrity under all experimental conditions. N IMPORTANT design criterion for nu-