Some chemical properties of 2,3-dihydro-4H-[1,3]thiazino[3,2-a]benzimidazol-4-one and 2-aryl-2,3-dihydro-4H-[1,3]thiazino[3,2-a]benzimidazol-4-ones

Britsun, V. N.; Esipenko, A. N.; Lozinskii, M. O.

doi:10.1007/s10593-006-0099-x

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“…Similarly, reaction of b-fused benzimidazole 491 with ammonia, hydrazine or benzylamine in refluxing ethanol gave products 543 (Scheme 173). 241 The same reaction with a 6-aryl group (Ph, 4-OMe-C 6 H 4 ) on the ARKAT USA, Inc 1,3-thiazin-4-one ring gave products 455 when R = H and NH 2 (70-86%) (Scheme 173), but benzylamine caused cleavage of both the S-C6 and N3-C4 bonds. 241…”

Section: Scheme 172mentioning

confidence: 99%

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Chemistry of 1,3-thiazin-4-ones and their derivatives, 1995 - mid-2018

Silverberg¹,

Moyer²

2019

Arkivoc

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This review updates an earlier review published in 1996 by Ryabukhin, Korzhavina, and Suzdalev, which covered the literature through 1994. It deals with the synthesis and reactivity of 1,3-thiazin-4-ones and their derivatives. These include reduced compounds, 2-imino or 2-amino compounds, compounds with fused arenes or heterocycles, bridged compounds, and compounds combining various of these attributes.

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Section: Scheme 172mentioning

confidence: 99%

“…However, when there was an aryl substituent on C6, treatment of b-fused benzimidazole 5,6-dihydro-1,3thiazin-4-ones 388 with 30% hydrogen peroxide in acetic acid led to cleavage of the S-C6 and N3-C4 bonds (Scheme 156). 156,241…”

Section: Scheme 155mentioning

confidence: 99%