Solvothermal Synthesis and Characterization of One-Dimensional [Mn(en)3]CdSb2Se5

Zhang, Lirong; Qi, Fei-Yan; Shele, Muge; Namila, E; Qi, Liming; Baiyin, Menghe

doi:10.1007/s10870-022-00953-1

Cited by 3 publications

(1 citation statement)

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“…Compounds 1 and 2 both have good photocurrent properties. Similar phenomena were found in some other selenides, such as K 2 HgSnSe 4 and [Mn(en) 3 ]CdSb 2 Se 5 …”

Section: Resultsmentioning

confidence: 99%

Transition Metal Germanium Chalcogenide Materials: Solvothermal Syntheses, Flexible Crystal, Structures, and Photoelectric Response Property

Cui,

Pan,

Wang

et al. 2024

Crystal Growth & Design

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The chalcogenides Cs 2 CdGeSe 4 (1), Cs 2 Hg 2 GeSe 5 (2), and Na 3 RbCu 8 Ge 3 S 12 (3) were synthesized by solvothermal condition. Germanium chalcogenides containing transition metals have flexible crystal structures. Compound 1 has a one-dimensional (1-D) chain structure consisting of anionic chain ∞ 1 {[GeCdSe 4 ] 2− } and Cs + cations. Compound 2 is a zero-dimensional (0-D) cluster structure consisting of anionic clusters of [GeHgSe 5 ] 2−and Cs + cations. Compound 3 is a three-dimensional (3-D) network structure consisting of a copper-rich [Cu 8 Ge 3 S 12 ] 4− anion and Na + and Rb + cations. Transition metal compounds with inorganic frameworks have abundant optical and electrical properties. We explored the photocurrent response of compounds 1−3. There are remarkable photocurrent densities for compounds 1−3, especially 1 with a density of 180 μA/cm 2 , which is superior to most germanium chalcogenides.

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“…Compounds 1 and 2 both have good photocurrent properties. Similar phenomena were found in some other selenides, such as K 2 HgSnSe 4 and [Mn(en) 3 ]CdSb 2 Se 5 …”

Section: Resultsmentioning

confidence: 99%