Solvent mediated synthesis of homoleptic tri and tetranuclear nickel complex derived from [Ni2(µ-SeC5H4N)2(dppe)2]2+ and theoretical studies

Chauhan, Rohit Singh; Moorthy, Shruti; Tyagi, A.K.; Torubaev, Yu. V.; Butcher, Raymond J.; Singh, Saurabh Kumar

doi:10.1016/j.jorganchem.2021.122177

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Journal of Organometallic Chemistry

2022

DOI: 10.1016/j.jorganchem.2021.122177

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Solvent mediated synthesis of homoleptic tri and tetranuclear nickel complex derived from [Ni2(µ-SeC5H4N)2(dppe)2]2+ and theoretical studies

Rohit Singh Chauhan

Shruti Moorthy

A.K. Tyagi

et al.

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2024

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Cited by 2 publications

References 58 publications

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Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

Nandeshwar

Tarannum²,

Singh³

et al. 2022

Polyhedron

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Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

Nandeshwar

Tarannum²,

Singh³

et al. 2022

Polyhedron

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A Spin-Frustrated Azide- and Alkoxide-Bridged Heterobimetallic Mixed-Valence Mn^IIMn^III₂Ni^II₄ Disc with S = 17/2 or 19/2

Kumar,

Tarannum,

Singh

et al. 2024

ACS Omega

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Seven-membered homometallic Fe III 7 , Mn III 3 Mn II 4 coordination clusters were previously reported to be spin-frustrated molecular discs. Herein, a mixed bimetallic and mixedvalence dicationic [Mn II Mn III 2 Ni II 4 (N 3 ) 4 (hmp) 10 ](NO 3 ) 2 (1 2+ (NO 3 ) 2 ) was isolated in pure form without scrambling of Ni/Mn ions. It was structurally characterized by single-crystal X-ray singlecrystal diffraction. The presence of Mn II ions at the center of the disc has been confirmed by EPR measurements. The magnetic studies suggest that complex 1 2+ (NO 3 ) 2 possesses spin frustration with spin ground states S = 17/2 and 19/2, which has been studied and supported by DFT calculation. The purity of 1 2+ (NO 3 ) 2 was confirmed by powder XRD measurements, and the ratio of Ni:Mn = 4:3 was further determined by SEM-EDX analysis.

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Solvent mediated synthesis of homoleptic tri and tetranuclear nickel complex derived from [Ni2(µ-SeC5H4N)2(dppe)2]2+ and theoretical studies

Cited by 2 publications

References 58 publications

Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

A Spin-Frustrated Azide- and Alkoxide-Bridged Heterobimetallic Mixed-Valence Mn^IIMn^III₂Ni^II₄ Disc with S = 17/2 or 19/2

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Solvent mediated synthesis of homoleptic tri and tetranuclear nickel complex derived from [Ni2(µ-SeC5H4N)2(dppe)2]2+ and theoretical studies

Cited by 2 publications

References 58 publications

Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

Antimony(III)-selenium complexes with synergetic effect between Sb Se bond and Sb⋯π interactions

A Spin-Frustrated Azide- and Alkoxide-Bridged Heterobimetallic Mixed-Valence MnIIMnIII2NiII4 Disc with S = 17/2 or 19/2

Contact Info

Product

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A Spin-Frustrated Azide- and Alkoxide-Bridged Heterobimetallic Mixed-Valence Mn^IIMn^III₂Ni^II₄ Disc with S = 17/2 or 19/2