2020
DOI: 10.3390/catal10111244
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Solvent Influence on Selectivity in α-Pinene Oxide Isomerization Using MoO3-Modified Zeolite BETA

Abstract: Natural source turpentine is an available source of α-pinene oxide. This compound’s value is especially given by the possibility of producing important compounds campholenic aldehyde and trans-carveol. In this work, we would like to present the usage of MoO3-modified zeolite BETA in α-pinene oxide isomerization concerning campholenic aldehyde and trans-carveol formation using a wide range of solvents. Catalyst calcination temperature also influenced the reaction course (selectivity to desired compounds and rea… Show more

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Cited by 14 publications
(12 citation statements)
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References 36 publications
(70 reference statements)
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“…Moreover, high selectivity to TCV can be linked to an easier proton transfer to the tertiary cation in the presence of a basic solvent, such as N , N -dimethylacetamide applied in the current work. On the contrary, for nonpolar and nonbasic solvents, selectivity to campholenic aldehyde is elevated …”
Section: Resultssupporting
confidence: 93%
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“…Moreover, high selectivity to TCV can be linked to an easier proton transfer to the tertiary cation in the presence of a basic solvent, such as N , N -dimethylacetamide applied in the current work. On the contrary, for nonpolar and nonbasic solvents, selectivity to campholenic aldehyde is elevated …”
Section: Resultssupporting
confidence: 93%
“…It was suggested that the formation of trans -carveol over Lewis acid sites (Scheme ) occurs through formation of a tertiary cation C′, similar to cation C in Scheme , which was supposed to be more stable than a secondary cation of type A′. Moreover, high selectivity to TCV can be linked to an easier proton transfer to the tertiary cation in the presence of a basic solvent, such as N , N -dimethylacetamide applied in the current work. On the contrary, for nonpolar and nonbasic solvents, selectivity to campholenic aldehyde is elevated …”
Section: Resultsmentioning
confidence: 99%
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“…Solvent influence on the course of any reaction can be crucial [36]. The solvent influence on our reaction is visible in Table 6, rows 6-10.…”
Section: Influence Of the Solventmentioning
confidence: 99%