The coating Fe3O4 using humic acid (HA) to form was conducted and applied for phenol sorption. Fe3O4/HA was prepared using co-precipitation method in an alkaline condition using ammonium hydroxide and the addition of HA with mass ratios of Fe3O4 and HA = 20:1, 10:1, 10:2, 10:3 0,55, 0,56, 0,58, 0,56 mmol/g untuk Fe3O4/AH pada perbandingan massa 20:1, 10:1, 10:2, 10:3