Solvent Effects on the Electronic Spectrum of C60

Gallagher, Sean H.; Armstrong, Robert S.; Lay, Peter A.; Reed, Christopher A.

doi:10.1021/j100016a015

Cited by 120 publications

(100 citation statements)

References 7 publications

(9 reference statements)

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“…On one hand, both MEH-PPV and C 60 have a large -conjugated system in which -interaction may change the configuration of MEH-PPV. 9 On the other hand, the photo-induced charge transfer from excited MEH-PPV to C 60 was rapid. Upon this …”

Section: Resultsmentioning

confidence: 99%

The interaction between conjugated polymer and fullerenes

Zheng

Bai

et al. 1998

J. Appl. Polym. Sci.

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ABSTRACT:The fluorescence of Poly(2-methoxy,5-(2Ј-ethylhexloxy)-p-phenylene-vinylene) (MEH-PPV) quenched by fullerenes was examined, and the results indicate that this quenching is not dynamic. Strong interaction in the excited state between them may be caused by the photoinduced charge transfer and -conjugated system interaction. More direct and convincing evidence of the charge transfer complex are presented.

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Section: Resultsmentioning

confidence: 99%

The interaction between conjugated polymer and fullerenes

Zheng

Bai

et al. 1998

J. Appl. Polym. Sci.

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“…As mentioned at the beginning of this subsection, also polar (charge-transfer) molecular compounds exist, which are usually obtained from solution of fullerenes and electrondonor species in a solvent common to both organic species [47,82,100]. One of the most studied examples is the salt formed by C 60 with tetrakisdimethylaminoethylene (TDAE), where one electron is transferred from TDAE to the LUMO orbital of Buckminsterfullerene.…”

Section: B2 Molecular Compounds Solvates and Hydrates Of Fullerenementioning

confidence: 99%

Solid State Physicochemical Properties and Applications of Organic and Metallo- Organic Fullerene Derivatives

Mitsari¹,

Romanini²,

Zachariah³

et al. 2016

COC

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Abstract:We review the fundamental properties and main applications of organic derivatives and complexes of fullerenes in the solid-state form. We address in particular the structural properties, in terms of crystal structure, polymorphism, orientational transitions and morphology, and the electronic structure and derived properties, such as chemical activity, electrical conduction mechanisms, optical properties, heat conduction and magnetism. The last two sections of the review focus on the solid-state optoelectronic and electrochemical applications of fullerene derivatives, which range from photovoltaic cells to field-effect transistors and photodetectors on one hand, to electron-beam resists, electrolytes and energy storage on the other.

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“…It should be noted that a change in the quadrupole moment has been predicted by Gallagher et al in order to account for their observed solvatochromism shifts of C 6 0 . 16 The energetic of four symmetry-reduced structures at various level of treatment are listed in Table 1, excluding the T h symmetry structure, which was energetically identical to the I h conformation. Relative Energy a…”

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confidence: 99%

Enhanced energetic stability and optical activity of symmetry-reduced C60

Manaa

2006

Chemical Physics Letters

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Solvent Effects on the Electronic Spectrum of C60

Cited by 120 publications

References 7 publications

The interaction between conjugated polymer and fullerenes

The interaction between conjugated polymer and fullerenes

Solid State Physicochemical Properties and Applications of Organic and Metallo- Organic Fullerene Derivatives

Enhanced energetic stability and optical activity of symmetry-reduced C60

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