Solvent Effects in Reactions of Phenylcyclopropyl Phenyl Ketones with Phosphorus Pentachloride<sup>1,2</sup>

Newman, Melvin S.; Ream, Bernard C.

doi:10.1021/jo01345a025

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Furan (20)1

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1970

1985

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Cited by 5 publications

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“…In recent years, the Lewis acid-catalysed ringopening of rigid cyclopropyl ketones has been studied by Stork and co-workers' with a view to synthesizing polycyclic systems with natural steroid stereochemistry. They found, for example, that the cyclopropyl ketone (3), on reaction with stannic chloride in moist benzene, gave two bicyclic products (4,5). Grieco and Finkelhor' similarly cyclized the non-rigid cyclopropyl ketone (6).…”

Section: Furan (20)mentioning

confidence: 99%