Solvent effect on the complex formation of polyvinylpyrrolidone and polymonomethyl itaconate

Anasagasti, M.; Valenciano, R.; Bivas, L.; Katime, Issa

doi:10.1007/bf00295971

Cited by 6 publications

References 9 publications

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Physicochemical, Solution, and Colloidal Properties of Pyrrolidone and Caprolactam‐Based Polymers

McMullen

Clark

Ozkan

et al. 2021

Handbook of Pyrrolidone and Caprolactam Based Materials

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Poly(vinylpyrrolidone) (PVP) is one of the most widely used polymers for numerous biomedical, pharmaceutical, personal care, and industrial applications. This chapter begins with an introduction to the solution properties of PVP as manifested in a number of different important parameters to describe the physicochemical properties of the polymer in aqueous solutions. One of the key features of PVP is its good solubility in both water and organic solvents. The complexation of PVP with polyphenols is the basis for a variety of applications. The generation of binding isotherms provides insight into the interactions between polymers and cosolutes. There is an increasing interest in interpolymer complexes or polymer‐polymer complexes formed by mixing two or more interacting polymers in solution, since they are used to generate multilayered soft nanomaterials, such as self‐assembled films or nanoparticles. There has been significant interest in subcritical and supercritical fluid technology as substitutes for organic solvents.

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Physicochemical, Solution, and Colloidal Properties of Pyrrolidone and Caprolactam‐Based Polymers

McMullen

Clark

Ozkan

et al. 2021

Handbook of Pyrrolidone and Caprolactam Based Materials

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Formation of interpolymer complexes between poly(monoethyl itaconate) and poly(N‐vinyl‐2‐pyrrolidone)

Cesteros

Meaurio

Katime

1994

Polymer International

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This paper reports on the interpolymer complex formation and polymer blends between poly(monoethyl itaconate) (PMEI) and poly(N‐vinyl‐2‐pyrrolidone) (PVP). The formation of the interpolymer complex was found to depend upon the solvent medium. Stoichiometry of the complexes prepared from methanol solutions, as calculated from elemental analysis, is close to 1 : 1. Specific interactions of PMEI/PVP complexes and blends of these polymers have been characterized by FTIR. Strong hydrogen bonding for complexes and blends has been found. A calorimetric study of the complexes and blends has been performed over a wide temperature range.

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Interpolymer Complexation and Miscibility Enhancement by Hydrogen Bonding

Jiang

Xiang

et al. 1999

Polymer Synthesis/Polymer-Polymer Complexation

242

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Solvent effect on the complex formation of polyvinylpyrrolidone and polymonomethyl itaconate

Cited by 6 publications

References 9 publications

Physicochemical, Solution, and Colloidal Properties of Pyrrolidone and Caprolactam‐Based Polymers

Physicochemical, Solution, and Colloidal Properties of Pyrrolidone and Caprolactam‐Based Polymers

Formation of interpolymer complexes between poly(monoethyl itaconate) and poly(N‐vinyl‐2‐pyrrolidone)

Interpolymer Complexation and Miscibility Enhancement by Hydrogen Bonding

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