1969
DOI: 10.1021/i260032a021
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Solvent Design for Chemical Reactions

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Cited by 27 publications
(19 citation statements)
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References 16 publications
(21 reference statements)
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“…The liquid-phase Diels-Alder dimerization of cyclopentadienc to form a-dicyclopentadiene at 25°C has been studied in a number of solvents. Solvent effects have also been predicted by Wong and Eckert (1969) using the Bransted-Bjerrum relationship in conjunction with the regular solution theory of Scatchard and Hildebrand. From Eq.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The liquid-phase Diels-Alder dimerization of cyclopentadienc to form a-dicyclopentadiene at 25°C has been studied in a number of solvents. Solvent effects have also been predicted by Wong and Eckert (1969) using the Bransted-Bjerrum relationship in conjunction with the regular solution theory of Scatchard and Hildebrand. From Eq.…”
Section: Resultsmentioning
confidence: 99%
“…A comparison of measured solvent effects with those calculated by Wong and Eckert and those predicted using UNIFAC are presented in Figure 1. References for the experimental data are compiled by Wong and Eckert (1969). The competitive hydrogenation of cyclohexene and acetone over a nickel catalyst at 25°C has been studied in a number of different solvents by Jungers et al (1958).…”
Section: Resultsmentioning
confidence: 99%
“…Expressions of this type have proven quite useful in predicting and correlating kinetic solvent effects for many nonpolar and polar molecular reactions (Eckert, 1967;Wong andEckert, 1969,1970;Eckert et al, 1974). The dielectric constant is an important property for kinetic solvent effects in reactions with significant electrical effects.…”
Section: Discussionmentioning
confidence: 99%
“…(16) lassen sich die Grenzwerte von ts/tM fur [MI + 0 und[S] + 0 ableiten: lim t S / t M = 0,5(vS/vM $-1 ) (18). ISlF+o Da Vs/VM der ublicherweise verwendeten Losungsmittel/ Monomer-Kombinationen nicht zu stark von 1 abweichen, sind beide Grenzwerte annahernd gleich.…”
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