Solvent Content Controlling Strategy for Cocrystallizable Polyesters Enables a Stress‐Free Two‐Way Shape Memory Effect with Wider Service Temperatures
Qi Guo,
Yaoming Zhang,
Hongwei Ruan
et al.
Abstract:AbstractIt is challenging to enhance the stress‐free two‐way shape memory (stress‐free TWSM) effect to obtain a wide range of response temperatures. Herein, a polycaprolactone (PCL)/poly(ω‐Pentadecalactone) (PPDL) was photocured under UV light irradiation in the solvent of 1,1,2‐trichloroethane (TCA), to obtain a series of cross‐linked polyesters (CPES). Controlling solvent content (SC) which was removed after the polymerization allows the yielded CPES to perform a regulatable thermodynamic and stress‐free TW… Show more
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