Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties

Synthesis, structural properties, and catalytic behavior of Cu-BTC and mixed-linker Cu-BTC-PyDC in the oxidation of benzene derivatives

“…In the first approach, the MOF plays simply the role of a support material, which is used for immobilization of the active component in the form of nanoparticles or clusters inside the pores of the material [3][4][5][6][7][8]. In contrast to that, also the MOF structure itself can contain catalytically active centers at the organic linker molecules of the framework.…”

Study of Synthesis and Characterization of Metal-Organic Frameworks Mof-5 as Hydrogen Storage Material

“…Doping kation Li terhadap MOF dapat meningkatkan binding energy H 2 sehingga kapasitas penyerapan hidrogen lebih tinggi (Dalach et al, 2008). Efek spillover dengan loading nanopartikel Pt (Kim et al, 2015) atau impregnasi dengan Pd pada MOF-5 (Sabo et al, 2007) DAFTAR PUSTAKA…”

One-potN-alkylation of primary amines to secondary amines by gold clusters supported on porous coordination polymers

“…It is worth noting that Au clusters supported on Al-MIL53 could promote the one-pot N-alkylation of 4 with 5 under inert atmosphere without O 2 and H 2 to produce 7 in the co-presence of base (entry 5), whereas Au NPs on CPL-2 and on MOF-5 could not (entry 7,8). It can be assumed that hydrogen atoms generated by the dehydrogenation of 4 are used for the hydrogenation of 6 to give 7.…”

“…It has been reported that Pd (7,8), Cu (7), Ru (9) clusters in the range of 1-3 nm could be deposited on or in PCPs by chemical vapor deposition (CVD) whereas Au clusters with diameters of smaller than 2 nm had been hardly obtained by CVD because of the weak interactions of Au with PCP frameworks (7). Recently, we have developed a new deposition technique that enables the deposition of Au as clusters on PCPs and have found that the supported Au clusters and Au NPs smaller than 5 nm are catalytically active for the aerobic oxidation of alcohols (10).…”

“…Porous coordination polymers (PCPs) with highly ordered nanometer-sized porous structures have been attracting growing interests as supports for metal clusters smaller than 2 nm in diameter (7)(8)(9)(10)(11). It has been reported that Pd (7,8), Cu (7), Ru (9) clusters in the range of 1-3 nm could be deposited on or in PCPs by chemical vapor deposition (CVD) whereas Au clusters with diameters of smaller than 2 nm had been hardly obtained by CVD because of the weak interactions of Au with PCP frameworks (7).…”