Solution calorimetry as a complementary tool for the determination of enthalpies of vaporization and sublimation of low volatile compounds at 298.15 K

Solomonov, Boris N.; Varfolomeev, Mikhail A.; Nagrimanov, Ruslan N.; Novikov, Vladimir B.; Zaitsau, Dzmitry H.; Verevkin, Sergey P.

doi:10.1016/j.tca.2014.05.033

Cited by 79 publications

(48 citation statements)

References 67 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Details on the experimental procedure and equipment were published previously. 3 The refractometer was calibrated with pure water. Experimental refractive indices measured in this work are collected in the Supporting Information (see Table S3).…”

Section: Methodsmentioning

confidence: 99%

“…The experimental procedure was described elsewhere. 3 All experiments including calibrations were carried out at 298.15 ± 0.01 K. Experimental results on d i are collected in the Supporting Information (see Table S3). …”

Section: Methodsmentioning

confidence: 99%

“…16 Unfortunately, aromatic and polyaromatic compounds generally have low solubility in cyclohexane and better solubility in benzene. Due to this reason we were forced to adjust empirical coefficients a s and b s for benzene as the solvent 3 …”

Section: Methodsmentioning

confidence: 99%

See 2 more Smart Citations

Enthalpies of Vaporization and Sublimation of the Halogen-Substituted Aromatic Hydrocarbons at 298.15 K: Application of Solution Calorimetry Approach

et al. 2015

Self Cite

View full text Add to dashboard Cite

Recently, the solution calorimetry has been shown to be a valuable tool for the indirect determination of vaporization or sublimation enthalpies of low volatile organic compounds. In this work we studied 16 halogen-substituted derivatives of benzene, naphthalene, biphenyl, and anthracene using a new solution calorimetry based approach. Enthalpies of solution at infinite dilution in benzene as well as molar refractions for the chlorine-, bromine-, and iodine-substituted aromatics were measured at 298.15 K. Vaporization and sublimation enthalpies of these compounds at 298.15 K were indirectly derived from the solution calorimetry data. In order to verify results obtained by using solution calorimetry, vaporization/sublimation enthalpies for 1,2-, 1,3-, 1,4-dibromobenzenes, 4-bromobiphenyl, and 4,4′-dibromobiphenyl were additionally measured by using the well established transpiration method. Experimental data available in the literature were collected and evaluated in this work for the sake of comparison with our own results. Vaporization and sublimation enthalpies of halogen-substituted aromatics under study derived by using solution calorimetry approach have been in a good agreement with those measured by conventional methods. This fact approves using of solution calorimetry for determination or validation of sublimation/vaporization enthalpies for different aromatic compounds at reference temperature 298.15 K, where the conventional experimental data are absent or in disarray. Evaluated in this work a data set has been used to establish a simple group additivity scheme for prediction of vaporization enthalpies for halogen-substituted aromatic hydrocarbons.

show abstract

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

See 1 more Smart Citation

Enthalpies of Vaporization and Sublimation of the Halogen-Substituted Aromatic Hydrocarbons at 298.15 K: Application of Solution Calorimetry Approach

et al. 2015

Self Cite

View full text Add to dashboard Cite

show abstract

“…The verification of the calorimetric procedure was performed by measuring the reference [22] solution enthalpy of potassium chloride in water. The detailed description of the standard solution procedure was published elsewhere [16,23]. All experimental enthalpies of solution of halogen-substituted adamantanes in cyclohexane measured in this work are presented in Table S2.…”

Section: Solution Calorimetry Enthalpies Of Solution In Cyclohexanementioning

confidence: 99%

“…In order to support transpiration results on sublimation enthalpies we used the independent complementary method based on solution calorimetry measurements [16][17][18][19]. Enthalpies of solution at T = 298.15 K of adamantane, 1-Cl-adamantane, 2-Cl-adamantane, 1-Br-adamantane, and 1-Br- …”

Section: Introductionmentioning

confidence: 99%

Six-membered ring aliphatic compounds: A search for regularities in phase transitions

et al. 2016

Self Cite

View full text Add to dashboard Cite

Thermodynamic properties, mechanical properties and interatomic potential in solids: a Shou-Shi-Ling ( ) game

Benassi

Fan

2021

Continuum Mech. Thermodyn.

View full text Add to dashboard Cite

Solution calorimetry as a complementary tool for the determination of enthalpies of vaporization and sublimation of low volatile compounds at 298.15 K

Cited by 79 publications

References 67 publications

Enthalpies of Vaporization and Sublimation of the Halogen-Substituted Aromatic Hydrocarbons at 298.15 K: Application of Solution Calorimetry Approach

Enthalpies of Vaporization and Sublimation of the Halogen-Substituted Aromatic Hydrocarbons at 298.15 K: Application of Solution Calorimetry Approach

Six-membered ring aliphatic compounds: A search for regularities in phase transitions

Thermodynamic properties, mechanical properties and interatomic potential in solids: a Shou-Shi-Ling ( ) game

Contact Info

Product

Resources

About