“…[125] Addition of 2,6-dihalophenols to Zn[N(SiMe 3 ) 2 ] 2 gave four-coordinate, dimeric zinc phenoxides with coordinated THF solvent molecules. [125,127] To probe this theory, phosphane (PCy 3 , PMe 3 , etc.) Analysis of the PCHC revealed PDIs of 6.0, molecular weights of 42 000 g mol À1 , a T g of 115 8C, and > 99 % carbonate linkages.…”