“…The low permeability of aquitards coupled with high sorption capacity confers importance to them as protective barriers keeping drinking water aquifers safe from contamination [Bear, 1988;Neuzil, 1986;Starr et al, 1985;Sudicky et al, 1985] or in isolating wastes disposed in the subsurface [Desaulniers et al, 1981;Hendry et al, 2015;Starr et al, 1985;Sudicky et al, 1985]. Recent interest has also focused on aquifer-aquitard solute exchange related to long-term contaminant sequestration [Cuevas et al, 2009[Cuevas et al, , 2012Mazurek et al, 2011;Sudicky et al, 1985;Zhang et al, 2012] and aquitards acting as contaminant sources during back diffusion to aquifers [Chapman and Parker, 2005;Ball, 1998, 2002;Parker et al, 2004;Aral, 1992a, 1992b;Yang et al, 2015Yang et al, , 2016. aquifers where advection is the primary process, probably due to the high cost and difficulty in obtaining profiles of ions or isotopes and extracting porewaters from aquitards [Desaulniers et al, 1981;Mazurek et al, 2011].…”