Solubility of Solids and Liquids in Supercritical Fluids

Aim, Karel; Fermeglia, Maurizio

doi:10.1002/0470867833.ch13

Cited by 8 publications

(5 citation statements)

References 220 publications

(168 reference statements)

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“…Many researchers have conducted comprehensive studies in this field to investigate various types of highpressure phase equilibria (Christov and Dohrn, 2002;Dohrn and Brunner, 1995;Fornari et al, 1990;Dohrn et al, 2010;Fonseca et al, 2011). In addition, Aim and Fermeglia (2002)…”

Section: Experimental Methods Of Solubility Measurementmentioning

confidence: 99%

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Rad

Karimi-Sabet

Varaminian

2019

Braz. J. Chem. Eng.

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Due to the importance of supercritical fluid technology (SFT) in different industries, it has been the subject of intense research in recent decades. Solubility is a key concept in SFT. In fact, obtaining knowledge about the theoretical concepts of solubility and related experimental measurement methods can be useful in developing and improving the quality of research in this field. This study reviews the fundamental knowledge of solubility in supercritical fluids and investigates the significant topics in this field, including high-pressure phase behavior, experimental measurement methods, modeling, and molecular simulation of solubility.

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Section: Experimental Methods Of Solubility Measurementmentioning

confidence: 99%

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Rad

Karimi-Sabet

Varaminian

2019

Braz. J. Chem. Eng.

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“…The solubility measurements were carried out using a flow apparatus based on the principles of the transpiration method described in literature . A schematic diagram of the apparatus has been described in detail previously , and is shown in Figure S1 (see Supporting Information).…”

Section: Methodsmentioning

confidence: 99%

Solubilities of Some Chlorophenols in Supercritical CO₂ in the Presence and Absence of Cosolvents

Garlapati

Madras

2009

J. Chem. Eng. Data

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The solubilities of three chlorophenols, namely, 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol, in supercritical carbon dioxide were determined at temperatures from (308 to 318) K in the pressure range of (8.8 to 15.6) MPa. The solubilities were determined both in the absence of cosolvents and in the presence of two cosolvents, methanol and acetone. The solubilities (in the absence of cosolvents) in mole fraction of 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol at 308 K were in the range of (0.0113 to 0.0215), (0.0312 to 0.0645), and (0.008 to 0.0173), respectively. The solubilities of the chlorophenols followed the order 2,4-dichlorophenol > 4-chlorophenol > phenol > 2,4,6-trichlorophenol > pentachlorophenol. The solubility data were correlated with the Charstil model and with the Mendez-Santiago and Teja model. The overall deviation between the experimental data and the correlated results was less than 6 % in averaged absolute relative deviation (AARD) for both of the models.

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“…The solubility measurements of n -(4-ethoxyphenyl)ethanamide were carried out using a flow apparatus based on the principle of saturation method, which has described in literature. − A schematic diagram of the apparatus is shown in Figure S1 (see Supporting Information). The carbon dioxide was pressurized with a pump (model: Jasco PU-1580-CO 2 ) and operated in a constant flow mode, and the pressure was maintained within ± 0.2 MPa with a back pressure regulator (model: Jasco BP-158081).…”

Section: Methodsmentioning

confidence: 99%

Solubility of n-(4-Ethoxyphenyl)ethanamide in Supercritical Carbon Dioxide

Garlapati

Madras

2009

J. Chem. Eng. Data

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The solubility of a drug, n-(4-ethoxyphenyl)ethanamide (phenacetin), in supercritical carbon dioxide was determined by a saturation method at (308, 318, and 328) K from (9 to 19) MPa. The solubilities in mole fraction of n-(4-ethoxyphenyl)ethanamide in supercritical carbon dioxide were in the range of 1.29 • 10 -5 to 2.88 • 10 -5 , 1.13 • 10 -5 to 3.65 • 10 -5 , and 0.91 • 10 -5 to 4.28 • 10 -5 at (308, 318, and 328) K, respectively. The solubility data were correlated with the Peng-Robinson equation of state models and the Me ´ndez-Santiago and Teja model.

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Solubility of Solids and Liquids in Supercritical Fluids

Cited by 8 publications

References 220 publications

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Solubilities of Some Chlorophenols in Supercritical CO₂ in the Presence and Absence of Cosolvents

Solubility of n-(4-Ethoxyphenyl)ethanamide in Supercritical Carbon Dioxide

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Solubility of Solids and Liquids in Supercritical Fluids

Cited by 8 publications

References 220 publications

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Solubilities of Some Chlorophenols in Supercritical CO2 in the Presence and Absence of Cosolvents

Solubility of n-(4-Ethoxyphenyl)ethanamide in Supercritical Carbon Dioxide

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Solubilities of Some Chlorophenols in Supercritical CO₂ in the Presence and Absence of Cosolvents