2020
DOI: 10.1149/09810.0415ecst
|View full text |Cite
|
Sign up to set email alerts
|

Solubility of Rare Earth Oxides in Fused Alkali and Alkaline Earth Halides

Abstract: Solubility of rare earth oxides in mixtures of alkali or alkaline earth halides was determined by the method of isothermal saturation at the temperatures up to 1400oC. The melts studied included CaCl2–CaF2 (20 or 75 mol. % CaF2), BaCl2–BaF2 (15 or 73 mol. % BaF2), equimolar CaF2–BaF2 and eutectic NaCl–NaF mixtures. Melting points of the salt mixtures were determined by differential thermal analysis and effect of added rare earth oxide on the melting point was considered. Solubility of yttrium, lanthanum, ceriu… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
1
0

Year Published

2023
2023
2023
2023

Publication Types

Select...
1

Relationship

1
0

Authors

Journals

citations
Cited by 1 publication
(1 citation statement)
references
References 11 publications
0
1
0
Order By: Relevance
“…[1][2][3][4] Depending on the experimental conditions the reaction led to precipitation of rare earths as oxychlorides or oxides, with higher temperatures favoring the oxide formation. 2,4 Low solubility of rare earth oxides in halide melts 5,6 allows proposing this method, for example, for removing rare earth fission products from chloride electrolytes.…”
mentioning
confidence: 99%
“…[1][2][3][4] Depending on the experimental conditions the reaction led to precipitation of rare earths as oxychlorides or oxides, with higher temperatures favoring the oxide formation. 2,4 Low solubility of rare earth oxides in halide melts 5,6 allows proposing this method, for example, for removing rare earth fission products from chloride electrolytes.…”
mentioning
confidence: 99%