Solubility of potassium cyanide in mixed aqueous and non-aqueous media; Gibbs free energies of transfer of the cyanide ion

Thermodynamic functions of transfer of single ions from water to nonaqueous and mixed solvents: Part I - Gibbs free energies of transfer to nonaqueous solvents

“…Numbers in parentheses designate solvents for which no value for the ion could be selected. H 1, 2, 3, (4), (5), (6), (7), (8), (9), (10), 12, (15), (16), (17), (18), (19), (20), 24, (25), (26), (27), (29), (30) …”

Preferential solvation of ions in mixed solvents. 6: Univalent anions in aqueous organic solvents according to the inverse Kirkwood–Buff integral (IKBI) approach

“…Contrarily, for cyanide transfer into aqueous acetone the D t G data [17] lead to selective hydration up to x Me 2 CO $ 0:45, whereas for perchlorate this limit is x Me 2 CO $ 0:25 (figure 6), beyond which limits both anions are preferentially hydrated but do not exclude the acetone from the first solvation shell. Finally, the transfer of cyanide into aqueous dimethylsulfoxide [31] shows (figure 11) preferential hydration of a magnitude between that of chloride and bromide. Figures 1 to 12 present the values of the preferential solvation parameters of several anions in mixtures of water with co-solvents.…”