Solubility of chloramine in organic liquids

Rao, Yaddanapudi Jagannadha; Viswanath, Dabir S.

doi:10.1021/je60064a024

Cited by 5 publications

(1 citation statement)

References 4 publications

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“…Therefore, excess enthalpy values available at the highest temperature were used ignoring the temperature dependence. Even if the excess enthalpies are of the order of 1-2 kJ mor1 as exemplified by the p-xylene-1,1,2,2-tetrachloroethane (11), temperature independence can be assumed for the area test without sacrificing a great deal of accuracy. However, when one calculates other properties like enthalpies of vaporization using excess enthalpies and heat capacities, care should be exercised.…”

Section: Thermodynamic Consistencymentioning

confidence: 99%

Isobaric vapor-liquid equilibriums of the p-xylene-1,1,1-trichloroethane system

Viswanath¹,

Rao²

1982

J. Chem. Eng. Data

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Isobaric vapor-liquid equilibria of the p -xylene-1,1,1-trlchloroethane system were measured at 685-mmHg pressure. Activity coefficients were evaluated and correlated. Vapor pressures of 1,1,1-trlchloroethane In the range of 600-1750 mmHg are also reported.This second paper on the vapor-liquid equilibria of p-xylene-chloroethane systems presents data for the p-xylene-1,1, 1-trichloroethane system. Previous studies have presented

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Section: Thermodynamic Consistencymentioning

confidence: 99%

Isobaric vapor-liquid equilibriums of the p-xylene-1,1,1-trichloroethane system

Viswanath¹,

Rao²

1982

J. Chem. Eng. Data

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A model for diazacyclopropane synthesis

Jagannadharao

Viswanath

1976

J. Appl. Chem.

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The formation of 3-methyl-3-ethyl diazacyclopropane, an intermediate in the manufacture of hydrazine and its derivatives, was studied by reacting chloramine, ammonia and methyl ethyl ketone in a semi-batch reactor provided with a stirrer. The conversion (based on chlorine) was found to increase with ammonia to chlorine ratio (8-20), agitator speed (1000-3000 rev/min), temperature (5-6S°C), and lower ketones. The reaction was mass transfer controlled and first order with respect to chloramine with an activation energy and frequency factor of 5.67 kcal/gmol and 4.61 s-1 respectively. The stirred cell model due to Gal-Or and Resnick represented the experimental data with an average absolute deviation of 5.3 %.

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Enthalpies of solution and solubilities of tin(IV) iodide and of germanium(IV) iodide

Burgess

Kijowski

1982

Inorganica Chimica Acta

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Solubility of chloramine in organic liquids

Cited by 5 publications

References 4 publications

Isobaric vapor-liquid equilibriums of the p-xylene-1,1,1-trichloroethane system

Isobaric vapor-liquid equilibriums of the p-xylene-1,1,1-trichloroethane system

A model for diazacyclopropane synthesis

Enthalpies of solution and solubilities of tin(IV) iodide and of germanium(IV) iodide

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