2014
DOI: 10.1016/j.fluid.2014.09.013
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Solubility of (+)-catechin in water and water-ethanol mixtures within the temperature range 277.6–331.2K: Fundamental data to design polyphenol extraction processes

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Cited by 74 publications
(41 citation statements)
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“…However, there is also a stronger entropic effect (i.e., more positive D diss S o values) for the (daidzin + tetrahydrofuran) mixture. The more positive are the values of D diss S o , the greater the degree of randomness or disorder of the solution and the more favourable is the dissolution process [29].…”
Section: Resultsmentioning
confidence: 99%
“…However, there is also a stronger entropic effect (i.e., more positive D diss S o values) for the (daidzin + tetrahydrofuran) mixture. The more positive are the values of D diss S o , the greater the degree of randomness or disorder of the solution and the more favourable is the dissolution process [29].…”
Section: Resultsmentioning
confidence: 99%
“…Although total polyphenol extraction from onion solid wastes was shown to decline at temperatures higher than 40 • C (Khiari et al, 2009), the effect of temperature on the extraction yield in polyphenols is in several instances positive Brahim et al, 2014;Qu et al, 2010), because higher temperatures facilitate polyphenol diffusion and increase solubility (Boussetta et al, 2011;Galanakis et al, 2013). In addition, the solubilisation of polyphenols such as catechin, has been shown to be endothermic and thus thermodynamically favoured at higher temperatures (Cuevas-Valenzuela et al, 2014). On the other hand, temperature cannot be increased beyond certain limits, as this has been proven detrimental to anthocyanins (Cacace and Mazza, 2002;Jing and Giusti, 2007;Monrad et al, 2010).…”
Section: Kinetics and The Effect Of Temperaturementioning
confidence: 99%
“…By contrast, total polyphenol extraction from OSW has been shown to decline at temperatures higher than 40˝C [20]. Furthermore, it has been demonstrated that solubilization of catechin, an abundant RGP constituent, is endothermic and, thus, thermodynamically favored at higher temperatures [21]. Similar phenomena may hold true for other RGP constituents too.…”
Section: Resultsmentioning
confidence: 98%