“…The main reason is that the volume of equilibrium cell for system R134a + PVA in this work is as small as 10 mL, which is more appropriate for the static method; while that for system CO 2 + PVA is 150 mL and more suitable for the dynamic method. Furthermore, it is found that most of the solubility measurements for solutes in SCCO 2 have been carried out using the dynamic method [37][38][39][40]; while the static method has been widely used in systems containing sub-R134a [18,19,41]. Both methods are reliable when applying the right experimental procedure.…”
“…The main reason is that the volume of equilibrium cell for system R134a + PVA in this work is as small as 10 mL, which is more appropriate for the static method; while that for system CO 2 + PVA is 150 mL and more suitable for the dynamic method. Furthermore, it is found that most of the solubility measurements for solutes in SCCO 2 have been carried out using the dynamic method [37][38][39][40]; while the static method has been widely used in systems containing sub-R134a [18,19,41]. Both methods are reliable when applying the right experimental procedure.…”
“…Tamura et al. 45 examined the effect of a functional substituent group addition onto the anthraquinone to the solubility changes in scCO 2 . They focused on the solubility data of 1-amino-4-hydroxyanthraquinone (C.I.…”
Section: Solubility Of Dyes In Supercritical Fluidsmentioning
confidence: 99%
“…[40][41][42][43][44] Ö zcan et al 40 measured the solubility for the same dye at 20 MPa and 353.15 K and obtained a value of 3.76 Â 10 -6 mol dye/mol CO 2 . Also, Muthukumaran et al 43 Tamura et al 45 examined the effect of a functional substituent group addition onto the anthraquinone to the solubility changes in scCO 2 . They focused on the solubility data of 1-amino-4-hydroxyanthraquinone (C.I.…”
Section: Solubility Of Dyes Based On Anthraquinone Structurementioning
This review highlights the great role of supercritical carbon dioxide fluid technology in textile dyeing processes. The unequivocal physical characteristics of supercritical carbon dioxide are presented and further researched to continue the development of high efficiency, compact dyeing to save energy and water in manufacturing processes. This review also focuses on the solubility of the dyes in scCO2 as well as the application of the technology to both synthetic and natural fabrics. Some factors relating to the economics of sustainable scCO2 technology are also outlined.
“…The behavior of solid solute in the liquid phase is determined by a ratio of the fugacity between pure liquid solute and the solid state at pressure ( P ) and temperature ( T ), which have reported elsewhere [ 4 , 16 , 17 , 18 ]. Moreover, the activity of substance obtained from the melting temperature and the melting enthalpy of compound.…”
Solubility of several anthraquinone derivatives in supercritical carbon dioxide was readily available in the literature, but correcting ability of the existing models was poor. Therefore, in this work, two new models have been developed for better correlation based on solid–liquid phase equilibria. The new model has five adjustable parameters correlating the solubility isotherms as a function of temperature. The accuracy of the proposed models was evaluated by correlating 25 binary systems. The proposed models observed provide the best overall correlations. The overall deviation between the experimental and the correlated results was less than 11.46% in averaged absolute relative deviation (AARD). Moreover, exiting solubility models were also evaluated for all the compounds for the comparison purpose.
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