The densities ρ, speeds of
sounds u, and
dynamic viscosities η of the pure ionic liquid (IL) 1-butyl-3-methylimidazolium
trifluoromethanesulfonate ([BMIM][CF3SO3]),
acetonitrile (ACN), N,N-dimethylformamide
(DMF), and of their binary and ternary mixtures as a function of mole
fraction of IL/solvent at various temperatures (298.15 to 323.15)
K with an interval of T = 5 K and at P = 0.1 MPa have been measured experimentally.
The excess molar volumes, V
E, excess molar
isentropic compressibilities, K
S,m
E and viscosity
deviations, Δη have been determined from the measured
data of ρ, u, and η of pure [BMIM][CF3SO3], ACN, DMF and of their binary/ternary mixtures
at studied compositions and temperatures. We have also calculated
the Gibbs free energy of activation, ΔG
* and an excess Gibbs free energy of activation for viscous
flow, ΔG
*E for
the studied binary mixtures. The V
E, K
S,m
E and Δη of the studied binary/ternary
mixtures are fitted to the Redlich–Kister polynomial equation.
The trends of variations of parameters varied with mole fraction of
IL and temperature and are discussed in terms of ion–ion, ion–dipole,
and dipole–dipole interactions. In this work, we have also
applied various semiempirical models to correlate the experimental
dynamic viscosity data and evaluated interactional parameters of the
studied binary mixtures. The excess molar volumes of each binary system
have also been correlated with the Prigogine–Flory–Patterson
(PFP) theory and have been found in good agreement with the experimental
values.