Abstract:Stable molecular clusters are of interest for targeted
deposition
in porous materials. In this work, we report the discovery of two
new molecular Ce–O clusters of composition [Ce6O4(OH)4(NO3)4(DMF)4(C7H4O2X)8]·(DMF)4(H2O)2 (1-X) and [Ce6O4(OH)4(H2O)6(NO3)6(C7H4O2X)6] (2-X) (X = −Cl, −CHO, and −Br).
Both cluster types contain a similar hexanuclear building unit, and
crystal structures were determined from single-crystal X-ray diffraction
or 3D electron diffraction data and subsequent Rietveld refinements
agains… Show more
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