Solubilities, and solution and solvation enthalpies, for nitrogen and hydrogen in liquid lithium

Adams, Paul F.; Down, Michael G.; Hubberstey, Peter; Pulham, R. J.

doi:10.1016/0022-5088(75)90052-1

Cited by 62 publications

(14 citation statements)

References 7 publications

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“…+ Gas Liquid Adams et al [69] Messer et al [78] Veleckis et al Ihle and Wu [76] using the mass spectrometric Knudsen effusion method are far from the data of all other authors.…”

Section: Liquidsmentioning

confidence: 90%

“…In the lithium-rich side of this system, the liquidus data of Adams et al [69] obtained by electric resistivity measurements were used to evaluate the thermodynamic parameters of the liquid phase. Liquidus data of Messer et al [78] obtained by thermal analysis were not considered in this work because lithium vaporization was not avoided fully by encapsulating the samples, leading to potential errors in the lithium-rich side of this system.…”

Section: G the Li-h Systemmentioning

confidence: 99%

“…Several authors have measured the thermodynamic properties and phase diagrams of the Li-H system [69,[73][74][75][76][77][78][79][80][81][82] that are of interest of lithium in nuclear technologies [73,77,82] and for hydrogen storage. Sangster and Pelton [83] prepared a complete critical review of all phase diagram and thermodynamic properties of the Li-LiH system.…”

Section: G the Li-h Systemmentioning

confidence: 99%

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Modeling the Hydrogen Solubility in Liquid Aluminum Alloys

Harvey

Chartrand

2010

Metall Mater Trans B

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The modeling of hydrogen solubility in multicomponent Al-(Li, Mg, Cu, and Si) liquid phase has been performed with a thermodynamic approach using the modified quasichemical model with the pair approximation (MQMPA). All hydrogen solubility data available in literature was assessed critically to obtain the binary parameters of the MQMPA model for the Al-H, Li-H, Mg-H, Cu-H, Zn-H, and Si-H melts. For the Li-H system, a new thermodynamic description of the stable solid lithium hydride was determined based on the c p found in literature. The thermodynamic model for the Al-Li system also was reassessed in this work to take into account the short-range ordering observed for this system. Built-in interpolation techniques allow the model to estimate the thermodynamic properties of the multicomponent liquid solution from the liquid model parameters of the lower order subsystems. A comparison of the calculated hydrogen solubility performed at various equilibrium conditions of temperature, pressure, and composition with the available experimental data found in the literature is presented in this work, as well as a comparison with some results from previous modeling.

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“…+ Gas Liquid Adams et al [69] Messer et al [78] Veleckis et al Ihle and Wu [76] using the mass spectrometric Knudsen effusion method are far from the data of all other authors.…”

Section: Liquidsmentioning

confidence: 90%

Section: G the Li-h Systemmentioning

confidence: 99%

Section: G the Li-h Systemmentioning

confidence: 99%

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Modeling the Hydrogen Solubility in Liquid Aluminum Alloys

Harvey

Chartrand

2010

Metall Mater Trans B

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“…The first data on the liquidus line in Li-LiH -LiD systems below 624˚C were published by a group of British scientists headed by Adams and Hubberstey [1,[5][6][7][8][9]. The solubility was determined from the change in the electrical resistance during the dissolution of H 2 or D 2 in lithium and from the precipitation at the time of saturation.…”

Section: Behavior Of Isothermmentioning

confidence: 99%

Thermodynamic Properties of Li-LiH (LiD, LiT) Systems. The Phase Diagram

Yakimovich¹,

Biryukova²

2012

OJPC

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The paper presents a comprehensive critical review and detailed analysis of the literature, published in the field of the phase diagram solution Li-LiH (LiD, LiT). Special attention is paid to the completeness of the source information on the paper's topic resulting in an extended reference list. Particularly, paper reviews rarely used sources including littleknown publications from research centers, proceedings of the international scientific meetings and dissertations. These publications were more thoroughly analyzed in order to make the information available to the scientific society.

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“…The solubility of hydrogen in liquid Li was determined by Adams et al [24], who reported the following empirical formula for the solubility as a function of temperature in the range 523 to 775 K:…”

Section: Ni Membrane As a LI Anodementioning

confidence: 99%

Li?H2 cells with molten alkali chlorides electrolyte

2005

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Li-H 2 thermally regenerative fuel cells were studied using molten alkali chlorides as the electrolyte at relatively lower temperature. The saturation solubility of LiH in three different alkali chloride eutectic melts (LiCl-KCl, LiClCsCl, and LiCl-KCl-CsCl) was determined based on equilibrium potential measurements for the hydrogen electrode. Both a Ni membrane electrode and porous Ni electrode were evaluated as the cathode of the cell. In addition, a single cell of a Li-H 2 fuel cell with a Ni membrane for the anode was constructed, and the electromotive force (emf) was measured. When the Ni membrane electrode performed as an anode with molten salt electrolyte saturated with LiH, the measured emf was similar to previously reported emf for other types of molten salt electrolyte. In conclusion, certain types of molten alkali chlorides can be used as the electrolyte of a thermally regenerative fuel cell at a relatively lower operating temperature at least above 598 K.

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Solubilities, and solution and solvation enthalpies, for nitrogen and hydrogen in liquid lithium

Cited by 62 publications

References 7 publications

Modeling the Hydrogen Solubility in Liquid Aluminum Alloys

Modeling the Hydrogen Solubility in Liquid Aluminum Alloys

Thermodynamic Properties of Li-LiH (LiD, LiT) Systems. The Phase Diagram

Li?H2 cells with molten alkali chlorides electrolyte

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