Solubilité des gaz respiratoires dans les bis(F-alky)-1.2 éthènes

Chemistry, Physical Chemistry, and Uses of Molecular Fluorocarbon−Hydrocarbon Diblocks, Triblocks, and Related Compounds—Unique “Apolar” Components for Self-Assembled Colloid and Interface Engineering

“…[215][216][217] The solubility of gaseous CO 2 in liquid diblocks and triblocks was typically 4-5 times larger than that of O 2 , a situation also found for FCs. 176,209 It should be noted, however, that solubility of CO 2 in any solvent is typically ten times larger than that of O 2 .…”

“…The solubility of oxygen, carbon dioxide, nitric oxide, xenon, and other gases in highly fluorinated liquids has been investigated from a fundamental standpoint, in a search for specific interactions, and because of its application potential, for example as biocompatible O 2 /CO 2 or NO carriers. ,,, F Cs and gases both have low cohesive energy densities, as reflected by very close Hildebrand parameters. The solubilities of O 2 in various liquid FnHm compounds are collected in Table .…”

IUPAC-NIST Solubility Data Series. 103. Oxygen and Ozone in Water, Aqueous Solutions, and Organic Liquids (Supplement to Solubility Data Series Volume 7)

“…Oxygen + Dichlorodifluoromethane; CCl 2 F 2 ; [75-71-8] Two laboratories report data on the system. 176 182,184,187,189,193 report data on the system. Three papers 182,189,193 report only one value.…”

“…The data from Refs. 182, 184, and 193 were combined in a linear regression 189,191,196 report data on the system. The agreement among the values reported for temperatures that range from 293.2 to 310.2 K is poor.…”

“…Oxygen + 1,1,1,2,2,3, 3,4,4,5,5,6,6,9,9,10,10,11,11,12, 12,13,13,14,14, Two papers 112a,b,189 report single values at one temperature. The mole fractions are 6.14 Â 10 À3 at 298 K 112a,b and 6.4 Â 10 À3 at 310 K. 189 The values are classed as tentative. …”