Dust-acoustic (DA) waves (DAWs) and their modulational instability (MI) have been investigated theoretically in a plasma system consisting of inertial opposite polarity (positively and negatively) warm adiabatic charged dust particles as well as inertialess non-extensive q-distributed electrons and nonthermal ions. A nonlinear Schrödinger (NLS) equation is derived by using the reductive perturbation method. It has been observed from the analysis of NLS equaion that the modulationally stable solitary DAWs give rise to the existence of dark envelope solitons, and that the modulationally unstable solitary DAWs give rise to the existence of bright envelope solitons or rogue structures. It is also observed for the fast mode of DAWs that the basic features (viz. stability of the DAWs, MI growth rate, amplitude and width of the DA rogue waves, etc.) are significantly modified by the related plasma parameters (viz. dust masses, dust charge state, non-extensive parameter q, and non-thermal parameter α). The results of our present investigation might be useful for understanding different nonlinear electrostatic phenomena in both space (viz. ionosphere and mesosphere) and laboratory plasmas (viz. high intensity laser irradiation and hot cathode discharge).PACS. PACS-key discribing text of that key -PACS-key discribing text of that key