Solid-state synthesis of single-phase nickel monophosphosulfide for the oxygen evolution reaction

Wang, Miao; Li, Xiaoguang; Peng, Tao; Zhang, Qitao; Kumar, Mohan; Zhao, Wei

doi:10.1039/d1dt02343h

Cited by 8 publications

(6 citation statements)

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Numerous wearable pressure sensors have been created as a result of the usage of electrospun nanofibers. These sensors have four different ways of functioning: capacitive [124], and triboelectric [125]. In light of this, electrode materials, conductive layers, or dielectric layers are all uses for electrospun nanofibers in pressure sensor assemblies.…”

Section: Applications Of Electrospun Nanofibersmentioning

confidence: 99%

Electrospun nanofibers synthesis enhancing the activity of energy storage devices/electrochemical and biosensor applications

Noor,

Saleem,

Furqan Mughal

et al. 2024

Electroanalysis

View full text Add to dashboard Cite

show abstract

Section: Applications Of Electrospun Nanofibersmentioning

confidence: 99%

Electrospun nanofibers synthesis enhancing the activity of energy storage devices/electrochemical and biosensor applications

Noor,

Saleem,

Furqan Mughal

et al. 2024

Electroanalysis

View full text Add to dashboard Cite

show abstract

“…In this paper, we will always refer to the structural dimensionality-rather than the thickness-when labeling PS materials as 3D, 2D, 1D, or 0D. PS compounds generally do not react with moisture or oxygen, except at the surface [25][26][27][28][29][30][31][32][33][34]. An exception is PSs with high alkali metal content, which [17] as of August 2023 among materials containing two anions among O, P, N, S, and an arbitrary number of metals.…”

Section: General Features Of Phosphosulfidesmentioning

confidence: 99%

“…In general, thiophosphates with 3D structural dimensionality have predominantly been investigated as solid electrolytes for Li and Na batteries [43] and as non-linear optical materials [44]. Thiophosphates with 2D structural dimensionality (often referred to as 'van der Waals' materials) have mainly been studied in the fields of Li and Na battery electrodes [45][46][47][48], ferroelectrics [49][50][51], magnetic materials [20,21,[52][53][54], and catalysts for the oxidation of S 2− [55], the reduction of CO 2 [56], the HER [30,36,[57][58][59][60] and the OER [28,33,60].…”

Section: Common Applications Of Phosphosulfidesmentioning

confidence: 99%

Phosphosulfide semiconductors for optoelectronics and solar energy conversion

Mittmann,

Crovetto

2024

J. Phys. Mater.

View full text Add to dashboard Cite

Inorganic phosphosulfides – materials containing phosphorus, sulfur, and at least one metal – are a vast and chemically-versatile family of materials. Benefiting from a wide range of possible phosphorus oxidation states, phosphosulfide semiconductors exist as thiophosphate compounds with various types of P-S polyanions, as genuine multi-anion compounds with or without P-P bonds, as solid solutions, and as many intermediate cases. Since metal phosphides and metal sulfides are among the highest-performing optoelectronic semiconductors, it seems reasonable to consider the phosphosulfide family as a potential pool of materials for solar cells, photoelectrochemical cells, and light-emitting diodes. Nevertheless, phosphosulfide semiconductors have very rarely been characterized with these applications in mind. In this perspective article, we reflect on the potential applicability of known and hypothetical phosphosulfides as light absorbers and emitters in optoelectronic devices. First, we distill the existing knowledge accessible through the Materials Project database, finding promising phosphosulfides among the compounds already present in the database and identifying what we see as the general advantages and challenges of phosphosulfides as optoelectronic materials. Then, we propose three concrete research directions aimed at finding novel high-quality phosphosulfide semiconductors with high light absorption coefficients, high carrier mobilities, and long carrier lifetimes. In particular, we argue that the versatility of phosphorus in this class of materials could potentially be exploited to engineer defect tolerance. Finally, we describe and explain the advantages of a custom synthesis setup dedicated to high-throughput exploration of thin-film phosphosulfides.

show abstract

“…PS compounds generally do not react with moisture or oxygen, except for at the surface. [21][22][23][24][25][26][27][28][29][30] An exception is PSs with high alkali metal content, which are often reported to be hygroscopic. [20] Various PSs are also reported to be stable in electrolyte solutions under a wide range of pH values.…”

Section: General Features Of Phosphosulfidesmentioning

confidence: 99%

Phosphosulfide semiconductors for optoelectronics and solar energy conversion

Mittmann,

Crovetto

2024

Preprint

View full text Add to dashboard Cite

Inorganic phosphosulfides – materials containing phosphorus, sulfur, and at least one metal – are a vast and chemically-versatile family of materials. Benefiting from a wide range of possible phosphorus oxidation states, phosphosulfide semiconductors exist as thiophosphate compounds with various types of P-S polyanions, as genuine multi-anion compounds with or without P-P bonds, as solid solutions, and as many intermediate cases. Since metal phosphides and metal sulfides are among the highest-performing optoelectronic semiconductors, it seems reasonable to consider the phosphosulfide family as a potential pool of materials for solar cells, photoelectrochemical cells, and light-emitting diodes. Nevertheless, phosphosulfide semiconductors have very rarely been characterized with these applications in mind. In this Perspective, we reflect on the potential applicability of known and hypothetical phosphosulfides as light absorbers and emitters in optoelectronic devices. First, we distill the existing knowledge accessible through the Materials Project database, finding promising phosphosulfides among the compounds already present in the database, and identifying what we see as the general advantages and challenges of phosphosulfides as optoelectronic materials. Then, we propose three concrete research directions aimed at finding novel high-quality phosphosulfide semiconductors with high light absorption coefficients, high carrier mobilities, and long carrier lifetimes. In particular, we argue that the versatility of phosphorus in this class of materials could potentially be exploited to engineer defect tolerance. Finally, we devise and describe a custom synthesis setup dedicated to high-throughput exploration of thin-film phosphosulfides.

show abstract

Solid-state synthesis of single-phase nickel monophosphosulfide for the oxygen evolution reaction

Abstract: High-performance and cost-effective nonprecious-metal catalysts are essential for next-generation oxygen evolution reaction (OER). However, the electrocatalysis of OER during water splitting is often carried out by noble metal catalysts, such...

Cited by 8 publications

References 62 publications

Electrospun nanofibers synthesis enhancing the activity of energy storage devices/electrochemical and biosensor applications

Electrospun nanofibers synthesis enhancing the activity of energy storage devices/electrochemical and biosensor applications

Phosphosulfide semiconductors for optoelectronics and solar energy conversion

Phosphosulfide semiconductors for optoelectronics and solar energy conversion

Contact Info

Product

Resources

About