Solid-state synthesis of a MOF/polymer composite for hydrodeoxygenation of vanillin

Karve, Vikram V.; Vieira, Adriana Neves; Stoian, Dragos; Trukhina, Olga; Queen, Wendy L.

doi:10.1039/d2cc03110h

Cited by 5 publications

(1 citation statement)

References 29 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In comparison with MOFs, different porous sorbents like zeolites, activated carbon, and others have several disadvantages, including material stability, high density, a lack of structural tenability, and low uptake capacity or selectivity. MOFs of different sizes and morphologies can be controllably produced using various synthesis methods such as sonication, electrochemical, hydro/solvothermal, mechanochemical, microwave, etc., [64][65][66][67]. The diverse MOFs obtained, which can be a class of 2D or 3D microporous materials, have emerged as prominent materials for water contaminant research.…”

Section: Mofs For Ecl Sensorsmentioning

confidence: 99%

Luminescent Metal–Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants

Sentic,

Trajkovic,

Manojlovic

et al. 2023

Materials

View full text Add to dashboard Cite

The modern lifestyle has increased our utilization of pollutants such as heavy metals, aromatic compounds, and contaminants that are of rising concern, involving pharmaceutical and personal products and other materials that may have an important environmental impact. In particular, the ultimate results of the intense use of highly stable materials, such as heavy metals and chemical restudies, are that they turn into waste materials, which, when discharged, accumulate in environmental water bodies. In this context, the present review presents the application of metal–organic frameworks (MOFs) in electrochemiluminescent (ECL) sensing for water pollutant detection. MOF composites applied as innovative luminophore or luminophore carriers, materials for electrode modification, and the enhancement of co-reaction in ECL sensors have enabled the sensitive monitoring of some of the most common contaminants of emerging concern such as heavy metals, volatile organic compounds, pharmaceuticals, industrial chemicals, and cyanotoxins. Moreover, we provide future trends and prospects associated with ECL MOF composites for environmental sensing.

show abstract

Section: Mofs For Ecl Sensorsmentioning

confidence: 99%

Luminescent Metal–Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants

Sentic,

Trajkovic,

Manojlovic

et al. 2023

Materials

View full text Add to dashboard Cite

show abstract

Carboxyl‐Decorated UiO‐66 Supporting Pd Nanoparticles for Efficient Room‐Temperature Hydrodeoxygenation of Lignin Derivatives

Yangcheng,

Li,

et al. 2024

Small

View full text Add to dashboard Cite

Hydrodeoxygenation (HDO) of lignin derivatives at room‐temperature (RT) is still of challenge due to the lack of satisfactory activity reported in previous literature. Here, it is successfully designed a Pd/UiO‐66‐(COOH)2 catalyst by using UiO‐66‐(COOH)2 as the support with uncoordinated carboxyl groups. This catalyst, featuring a moderate Pd loading, exhibited exceptional activity in RT HDO of vanillin (VAN, a typical model lignin derivative) to 2‐methoxyl‐4‐methylpheonol (MMP), and >99% VAN conversion with >99% MMP yield is achieved, which is the first metal‐organic framework (MOF)‐based catalyst realizing the goal of RT HDO of lignin derivatives, surpassing previous reports in the literature. Detailed investigations reveal a linear relationship between the amount of uncoordinated carboxyl group and MMP yield. These uncoordinated carboxyl groups accelerate the conversion of intermediate such as vanillyl alcohol (VAL), ultimately leading to a higher yield of MMP over Pd/UiO‐66‐(COOH)2 catalyst. Furthermore, Pd/UiO‐66‐(COOH)2 catalyst also exhibits exceptional reusability and excellent substrate generality, highlighting its promising potential for further biomass utilization.

show abstract

Hydrodeoxygenation of Bio-Oils (Eugenol, Vanillin, and Syringol)

Duong,

Phan

2024

Encyclopedia of Renewable Energy, Sustainability and the Environment

View full text Add to dashboard Cite

Solid-state synthesis of a MOF/polymer composite for hydrodeoxygenation of vanillin

Abstract: Here we demonstrate the use of a solid-state method to introduce a furan-thiourea polymer into the pores of a MOF, Cr-BDC. Next, the activity of the MOF-polymer composite containing Pd...

Cited by 5 publications

References 29 publications

Luminescent Metal–Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants

Luminescent Metal–Organic Frameworks for Electrochemiluminescent Detection of Water Pollutants

Carboxyl‐Decorated UiO‐66 Supporting Pd Nanoparticles for Efficient Room‐Temperature Hydrodeoxygenation of Lignin Derivatives

Hydrodeoxygenation of Bio-Oils (Eugenol, Vanillin, and Syringol)

Contact Info

Product

Resources

About