2011
DOI: 10.1002/ange.201003849
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Solid‐State Ion Channels for Potentiometric Sensing

Abstract: Äußerst wählerisch: Die Selektivitätsfilter biologischer Ionenkanäle dienen als Vorlage für die Entwicklung von ionophormodifizierten Festkörpernanoporen mit außergewöhnlicher Ionenselektivität (siehe Bild). Die potentiometrische Transduktion wird als eine Methode eingeführt, um die Ionensensorwirkung solcher Nanoporen zu demonstrieren.

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Cited by 19 publications
(13 citation statements)
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References 37 publications
(29 reference statements)
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“…Consequently, some nanomaterial-based potentiometric ion sensors have been developed without polymeric membranes matrix. For example, gold nanopores, which are fabricated by electroless deposition of gold onto the surface of track-etched polycarbonate nanopore membranes, are used to immobilize Ag + -selective ionophore to develop solid-state ion channels for potentiometric sensing [50]. The nanopore-based Ag + -ISE shows fast Nernstian potential responses with the LOD in the sub-nM range.…”
Section: Nanomaterial-based Potentiometric Sensing Membranesmentioning
confidence: 99%
“…Consequently, some nanomaterial-based potentiometric ion sensors have been developed without polymeric membranes matrix. For example, gold nanopores, which are fabricated by electroless deposition of gold onto the surface of track-etched polycarbonate nanopore membranes, are used to immobilize Ag + -selective ionophore to develop solid-state ion channels for potentiometric sensing [50]. The nanopore-based Ag + -ISE shows fast Nernstian potential responses with the LOD in the sub-nM range.…”
Section: Nanomaterial-based Potentiometric Sensing Membranesmentioning
confidence: 99%
“…Note that graphene layer is impermeable to even small atoms, such as helium [135]. However, recently, functionalized nanopores in graphene monolayers have been theoretically designed and have shown that they could serve as ionic sieves of high selectivity and transparency [63], in analogy to natural functional proteins [136][137][138]. In Fig.…”
Section: Ionic and Atomic Separation By Graphene Nanoporesmentioning
confidence: 99%
“…selective detection of target species in complex samples, still requires the use of selective receptors, either added to the sample solution [10,14] or confined to the nanopore interior [15,16]. In this latter approach either stochastic sensing [17,18] based on reversible binding of the target [19,20] or the more conventional approach in which the target is bound "irreversibly" into the nanopore sensing zone is used [21][22][23][24][25]. While there are exceptions [20], nanopore sensing requires nanopores with sizes that are comparable to, but larger than, that of the target.…”
Section: Introductionmentioning
confidence: 99%