Solid state decomposition studies on fluoroperoxo species of transition metals. Part X. Kinetics of the isothermal decomposition of K3TiO2F5

Jere, G.V.; Surendra, L.; Kaushik, Surender; Gupta, Mohini

doi:10.1016/0040-6031(81)85197-0

Cited by 9 publications

(2 citation statements)

References 7 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The constant volume equipment and experimental procedures for thermal and photochemical decomposition remained the same as reported earlier (7)(8)(9)(10)(11)(12). The kinetics were studied by measuring the pressure of oxygen evolved on decomposition; 4-5 mg (weighed on a Mettler H-54 balance) of compound was heated in a furnace electronically maintained at the desired temperature.…”

Section: Introductionmentioning

confidence: 99%

“…A kinetic study is a first important step in this direction. These factors prompted the authors to carry out the solid state thermal and photochemical decomposition of transition metal peroxo compounds on an elemental basis (7)(8)(9)(10)(11)(12) to determine the generalities, trends, or differences in the mode of decomposition by changing the cation, anion, or the nature of peroxide linkages etc. This paper is a part of this series and reports the isothermal and photochemical decomposition of K,TaO,F,.H,O.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O

Jere¹,

Surendra²,

Kaushik³

et al. 1982

Can. J. Chem.

View full text Add to dashboard Cite

The kinetics of the solid state isothermal and photochemical decompositions of K2TaO2F5.H2O have been studied by measuring the pressure of oxygen evolved in a constant volume apparatus. Isothermal decomposition of the sample was carried out in the temperature range 528 to 553 K. The reaction is predominantly deceleratory. The initial stage of the decomposition can be described by the unimolecular decay law whereas the later stage obeys the contracting volume equation. The activation energy values of the two processes are 120 and 90 kj mol−1, respectively. The photolysis of the compound at different intensities yields a pressure–time curve which can be described by the rate equations p = kt1/2. The rate of photolysis was found to be linearly dependent on intensity, indicating a monoexcitation process for peroxide decomposition.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O

Jere¹,

Surendra²,

Kaushik³

et al. 1982

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: SOLID STATE DECOMPOSITION STUDIES ON FLUOROPEROXO SPECIES OF TRANSITION METALS. PART X. KINETICS OF THE ISOTHERMAL DECOMPOSITION OF POTASSIU PENTAFLUOROPEROXOTITANATE(IV)

Jere¹,

Surendra²,

Kaushik³

et al. 1981

Chemischer Informationsdienst

View full text Add to dashboard Cite

show abstract

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XII. Kinetics of isothermal decomposition of K2VO(O2)2 F and K3Nb(O2)2F4

et al. 1982

View full text Add to dashboard Cite

Solid state decomposition studies on fluoroperoxo species of transition metals. Part X. Kinetics of the isothermal decomposition of K3TiO2F5

Cited by 9 publications

References 7 publications

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O

ChemInform Abstract: SOLID STATE DECOMPOSITION STUDIES ON FLUOROPEROXO SPECIES OF TRANSITION METALS. PART X. KINETICS OF THE ISOTHERMAL DECOMPOSITION OF POTASSIU PENTAFLUOROPEROXOTITANATE(IV)

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XII. Kinetics of isothermal decomposition of K2VO(O2)2 F and K3Nb(O2)2F4

Contact Info

Product

Resources

About

Solid state decomposition studies on fluoroperoxo species of transition metals. Part X. Kinetics of the isothermal decomposition of K3TiO2F5

Cited by 9 publications

References 7 publications

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K2TaO2F5.H2O

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K2TaO2F5.H2O

ChemInform Abstract: SOLID STATE DECOMPOSITION STUDIES ON FLUOROPEROXO SPECIES OF TRANSITION METALS. PART X. KINETICS OF THE ISOTHERMAL DECOMPOSITION OF POTASSIU PENTAFLUOROPEROXOTITANATE(IV)

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XII. Kinetics of isothermal decomposition of K2VO(O2)2 F and K3Nb(O2)2F4

Contact Info

Product

Resources

About

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O

Solid state decomposition studies on fluoroperoxo species of transition metals. Part XI. Kinetics of isothermal and photochemical decomposition of K₂TaO₂F₅.H₂O