Solid Solutions of the Alkali Halides. III. Lattice Constants of RbBr–RbCl and RbBr–KBr Solid Solutions

Durham, George S.; Alexander, Leroy E.; Pitman, Douglas T.; Golob, Helen R.; Klug, Harold P.

doi:10.1021/j150528a020

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2003

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X‐ray studies on quaternary system Rb_XK_1‐XBr_YCl_1‐Y

Mohanlal¹,

Padiyan²

2003

Cryst. Res. Technol.

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Single crystals of the quaternary crystalline solid solution system Rb x K 1-x Br y Cl 1-y have been grown by melt technique for three different compositions y = 0.25, 0.50 and 0.75, keeping x = 0.5 and X-ray diffraction studies have been carried out for each case independently, using spherically ground single crystals. The results indicate an enhancement of Debye-Waller B(total) factors for the compositions y = 0.25 and 0.75 whereas for the intermediate composition, y = 0.5, the factor B(total) is close to the end member value. This experimental investigation show that for this composition, the crystalline solid solution behaves like an end member crystal.

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