Solid-solid transition and solubility of even n-alkanes

Książczak, A.; Moorthi, Krzysztof; Nagata, Isamu

doi:10.1016/0378-3812(94)80058-8

Cited by 90 publications

(51 citation statements)

References 21 publications

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“…Another way to describe the solution behavior is Buchowski-Ksiazaczak h equation, which was suggested firstly by Buchowski et al [9]. This equation could fit the experimental data well with only two parameters and h for many systems [ [10][11][12][13]. In this work, the solubility data were also correlated with the Buchowski-Ksiazaczak h equation:…”

Section: Thermodynamic Modelingmentioning

confidence: 96%

Solubility of chlocyphos in different solvents

Sun¹,

Kang²,

Zhang³

et al. 2012

Fluid Phase Equilibria

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Section: Thermodynamic Modelingmentioning

confidence: 96%

Solubility of chlocyphos in different solvents

Sun¹,

Kang²,

Zhang³

et al. 2012

Fluid Phase Equilibria

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“…Their temperature behavior, as well as, their melting and boiling points (here, 37–522 °C) depend on their chain length. [ 30–34 ]…”

Section: Introductionmentioning

confidence: 99%

Alkanes as Intelligent Surface Thermometers: A Facile Approach to Characterize Short‐Lived Temperature Gradients on the Micrometer Scale

Eickelmann

Ronneberger

Zhang

et al. 2020

Adv Materials Inter

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Short‐lived micro‐sized thermal gradients are challenging to measure. Especially, in thin film processes and devices, it is important to know the exact temperature profile to assure process parameters and the stability of sensitive materials. Many theoretical models try to describe the occurring temperatures, but still lack in profound experimental data. Here, a facile approach is presented, which allows to measure confined temperature gradients with millisecond and micrometer precision. By casting a thin alkane film onto a substrate of interest, it is possible to reconstruct local temperature gradients by imaging the phase behavior and morphology of the alkane film with a simple optical microscope setup. Alkanes are inert and their melting and boiling temperatures depend on the chain length. This allows to measure temperatures between 37 and 522 °C on any surface. Furthermore, after thorough characterization of laser‐induced temperature gradients, this approach can be used to measure the phase transition behavior of complex thin film polymer mixtures.

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“…(6), is another way to describe the solution behavior, which was suggested firstly by Buchowski et al [16]. The Buchowski-Ksiazczak h equation could fit the experimental data well for many systems with only two parameters, and h [17][18][19][20]. In this paper, the solubility data were also correlated with the Buchowski-Ksiazczak h equation:…”

Section: Resultsmentioning

confidence: 93%