Solid-phase synthesis of iterative RAFT single unit monomer insertion adducts

Hakobyan, Karen; Noble, Benjamin B.; Xu, Jiangtao

doi:10.1039/d3py00828b

Polym. Chem.

2023

DOI: 10.1039/d3py00828b

|View full text |Cite

Solid-phase synthesis of iterative RAFT single unit monomer insertion adducts

Karen Hakobyan¹,

Benjamin B. Noble²,

Jiangtao Xu³

Abstract: In this Article, we disclose the use of a solid-phase methodology to synthesise iterative RAFT single unit monomer insertion (SUMI) adducts. This methodology features a reversible thiocarbonylthio protecting group and...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 50 publications

(65 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Synthesis of Dendrimer‐Like Molecules with Partial Carbon Chain via Iterative Single Unit Monomer Insertions

He,

Cui,

Liu

2024

Macromol. Rapid Commun.

View full text Add to dashboard Cite

Carbon‐chain dendritic polymers hold unique properties and promising applications. However, synthesizing carbon‐chain dendrimers, beyond conjugated ones, remains a challenge. Here, we described the use of the iterative single unit monomer insertions (SUMIs) technique for synthesizing 2.5 generation partial carbon‐chain dendrimers (G2.5), utilizing bismaleimide as the core, a maleimide‐trithiocarbonate conjugate as the branching unit, and indene as the spacer unit, following a divergent growth strategy. The optimized conditions for synthesizing the maleimide‐trithiocarbonate branching unit were a bismaleimide to trithiocarbonate ratio of 5:1 and a reaction time of 30 minutes. The structures were verified using 1H NMR, gel permeation chromatography, and MALDI‐TOF MS. A four‐arm star polymer was then synthesized using the G2.5 as the core. This synthesis of a partial carbon‐chain dendrimer establishes a foundational step towards creating all carbon‐chain ones and may open new application avenues in material science.This article is protected by copyright. All rights reserved

show abstract

Synthesis of Dendrimer‐Like Molecules with Partial Carbon Chain via Iterative Single Unit Monomer Insertions

He,

Cui,

Liu

2024

Macromol. Rapid Commun.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Solid-phase synthesis of iterative RAFT single unit monomer insertion adducts

Abstract: In this Article, we disclose the use of a solid-phase methodology to synthesise iterative RAFT single unit monomer insertion (SUMI) adducts. This methodology features a reversible thiocarbonylthio protecting group and...

Cited by 1 publication

References 50 publications

Synthesis of Dendrimer‐Like Molecules with Partial Carbon Chain via Iterative Single Unit Monomer Insertions

Synthesis of Dendrimer‐Like Molecules with Partial Carbon Chain via Iterative Single Unit Monomer Insertions

Contact Info

Product

Resources

About