“…The solid-phase extraction (SPE) is being utilized for preconcentration of heavy metals owing to its flexibility, economical and environmental-friendly, absence of emulsion, speed and simplicity, sampling in the field, safety and ease of automation [5]. Various sorbents have been used for preconcentration and determination of bismuth ions, such as polymeric materials [6,7], activated carbon [8], amberlite resin [9,10], modified sodium dodecyl sulfonate [11], silica gel [12], modified polyurethane foam [13] chromosorb-107 [14], rice husk [15] and some other solid substances. Unfortunately, these solid adsorbents have poor ion selectivity, which leads to high interference of other existing species with the target metal ions.…”