Solid-liquid equilibrium, thermodynamic modelling and the solvent effect of glimepiride in mono-solvents and binary mixed solvents

Gao, Xujie; Yu, Shaoming; Zhang, Guimin; Cheng, Yan; Wang, Shanshan

doi:10.1016/j.molliq.2022.119402

Cited by 10 publications

(3 citation statements)

References 40 publications

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“…J i is the model parameter. When combined with the modified Apelblat model, the modified Jouyban–Acree model − can be obtained and expressed as follows ln nobreak0em0.25em⁡ x 1 = B 1 + B 2 T + B 3 nobreak0em0.1em⁡ ln nobreak0em0.25em⁡ T + B 4 x 2 0 + B 5 x 2 0 T + B 6 ( x 2 0 ) 2 T + B 7 ( x 2 0 ) 3 T + B 8 ( x 2 0 ) 4 T + B x 2 0 nobreak0em0.1em⁡ ln nobreak0em0.25em⁡ T where B 1 to B 9 are the final model parameters.…”

Section: Theoretical Modelsmentioning

confidence: 99%

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Solubility Determination, Modeling, and Thermodynamic Analysis of 3-Aminophenol in Ten Monosolvents and Three Binary Mixed Solvents

Wu,

Xue,

Wang

et al. 2024

J. Chem. Eng. Data

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The solubilities of 3-aminophenol in monosolvents (ethyl acetate, isopropyl acetate, n-butyl acetate, amyl acetate, 1,2-dichloroethane, trichloromethane, benzene, 1,4-dioxane, tetrahydrofuran, and acetonitrile) and binary solvent mixtures (1,4-dioxane + water, tetrahydrofuran + water, and acetonitrile + water) were determined by a static gravimetric method at temperatures ranging from 283.15 to 328.15 K under atmospheric pressure. The solubility of 3-aminophenol in all solvent systems is positively correlated with temperature. In monosolvents, the solubility order of 3-aminophenol was as follows: THF > 1,4-dioxane > acetonitrile > ethyl acetate > isopropyl acetate > n-butyl acetate > amyl acetate > 1,2-dichloroethane > trichloromethane > benzene. The maximum solubility value occurred in 1,4-dioxane (x 1 = 0.3700 mol·mol–1, T = 328.15 K), and the minimum solubility value occurred in benzene (x 1 = 0.0005505 mol·mol–1, T = 288.15 K). In general, the solubility of 3-aminophenol in 1,4-dioxane + water and THF + water is greater than that in acetonitrile + water. There is a cosolvency phenomenon of 3-aminophenol in the solvents of 1,4-dioxane + water and acetonitrile + water. The experimental solubility data were correlated by the modified Apelblat model, the Yaws model, the λh model, the Sun model, the modified Jouyban–Acree model, and the Wilson model. The modified Apelblat model best fitted the experimental data among all of the selected models in monosolvents (with relative average deviation (RAD) and root-mean-square deviation (RMSD) less than 0.0156 and 0.001212, respectively) and binary solvent mixtures (with RAD and RMSD less than 0.0102 and 0.001408, respectively). Based on the experimental data of the solubility of 3-aminophenol in mono and binary solvents, the Wilson model was used to calculate the dissolution properties (Δdis H, Δdis S, and Δdis G). The results indicate that the dissolution process of 3-aminophenol is endothermic, entropy-increasing, and spontaneous. All of the selected models for both mono and binary solvents provide satisfactory correlation results.

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Section: Theoretical Modelsmentioning

confidence: 99%

“…J i is the model parameter. When combined with the modified Apelblat model, the modified Jouyban–Acree model − can be obtained and expressed as follows where B 1 to B 9 are the final model parameters.…”

Section: Theoretical Modelsmentioning

confidence: 99%

Solubility Determination, Modeling, and Thermodynamic Analysis of 3-Aminophenol in Ten Monosolvents and Three Binary Mixed Solvents

Wu,

Xue,

Wang

et al. 2024

J. Chem. Eng. Data

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“…The Apelblat model is a semiempirical model widely used to correlate the solubility data and temperature, which can be described as follows − where x 1 is the mole fraction of IHI, T is the absolute thermodynamic temperature, and A , B , and C are model parameters.…”

Section: Theoretical Modelsmentioning

confidence: 99%

Solubility Measurement and Correlation of Itraconazole Hydroxy Isobutyltriazolone in Four Kinds of Binary Solvent Mixtures with Temperature from 283.15 to 323.15 K

Dong,

Yu,

Wang

et al. 2023

ACS Omega

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The solubility of itraconazole hydroxy isobutyltriazolone (IHI) in four commonly used binary solvent mixtures of N,N-dimethylformamide (DMF) + water, DMF + ethanol, tetrahydrofuran (THF) + water, and THF + ethanol was determined with gravimetric method at temperatures ranging from 283.15 to 323.15 K under atmospheric pressure. The solubility of IHI in all selected solvents increases with the increase of temperature. The maximum solubility of IHI exists in the solvent of DMF + ethanol (0.06523 mol·mol–1, x 2 0 = 0.7, T = 323.15 K), while the minimum solubility exists in DMF + water (0.0003723 mol·mol–1, x 2 0 = 0.3, T = 283.15 K). There is a co-solvency phenomenon in the mixed solvents of DMF+ ethanol, THF + water, and THF + ethanol. Four thermodynamic models, including the modified Apelblat model, the Yaws model, the Sun model, and the modified Jouyban–Acree model, were selected to fit the solubility data of IHI. All the RAD values are less than 0.0484, and RMSD values are not more than 0.001319. The Yaws model and the modified Apelblat model fit the solubility data of IHI better than the other two models. All the selected four models can fit the solubility data of IHI well.

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Solubility Determination and Correlation of 1,3,5-Tribromobenzene in Five Kinds of Binary Mixed Solvents

Sun,

Wang,

Wan

et al. 2024

J Solution Chem

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Solid-liquid equilibrium, thermodynamic modelling and the solvent effect of glimepiride in mono-solvents and binary mixed solvents

Cited by 10 publications

References 40 publications

Solubility Determination, Modeling, and Thermodynamic Analysis of 3-Aminophenol in Ten Monosolvents and Three Binary Mixed Solvents

Solubility Determination, Modeling, and Thermodynamic Analysis of 3-Aminophenol in Ten Monosolvents and Three Binary Mixed Solvents

Solubility Measurement and Correlation of Itraconazole Hydroxy Isobutyltriazolone in Four Kinds of Binary Solvent Mixtures with Temperature from 283.15 to 323.15 K

Solubility Determination and Correlation of 1,3,5-Tribromobenzene in Five Kinds of Binary Mixed Solvents

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