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The chemical environment and the internal conditions of the furnaces and ladles are extremely aggressive for the refractories, so metallurgical industries demand refractory linings with greater durability and resistance to avoid unforeseen stoppages and to reduce the changes of the furnace lining. Therefore, the current work aims to evaluate the impact of the additions of ZrO 2 -nanoparticles (1, 3, and 5 wt. %) in magnesia-based bricks. A comparative study of the physical and chemical properties in bricks obtained using two cold pressing techniques (uniaxial and isostatic pressing) and two sintering temperatures (1550 and 1650 • C) was carried out. The microstructure and crystalline phase characteristics obtained after the heat treatments and the slag corrosion test was studied using scanning electron microscopy/electron dispersive X-ray spectroscopy (SEM/EDX) and X-ray diffraction (XRD). The results reveal that the sample with 5 wt. % of ZrO 2 nanoparticles (obtained by cold isostatic pressing and sintering at 1650 • C) has the lowest porosity and greatest resistance to penetration of blast furnace slag.2 of 20 to the martensitic transformation of the steels [2]. Zirconia confers to the refractories the following properties: strength, toughness, and chemical resistance under severe conditions. On the other hand, magnesium oxide (MgO) is a basic refractory material characterized by its refractoriness (high melting point, around 2800 • C). This material also has a thermal conductivity of 48 W/m·K at room temperature and has a good resistance to corrosion in the presence of basic material. Magnesia refractories, which are manufactured by mixing magnesium oxide with other materials (carbon, spinel, chromite, etc.) to obtain bricks with different shapes, are used in the lining of both furnaces and ladles employed in the metallurgical industry (basic oxygen furnace (BOF), electric arc furnaces (EAF), argon-oxygen-decarburization (AOD), ladle metallurgical furnaces (LMF), cement kilns and furnaces for nonferrous materials [3]).The main consumer of magnesia-based refractory bricks is the metallurgical industry, and particularly the iron and steelmaking industry, where they are mainly used in the slag line of the LMF, in the EAF and in the BOF [4]. Other consumers of magnesia bricks (magnesia-chromite) are the submerged arc furnaces (SAF) used in the copper manufacturing process, because of the resistances to the chemical degradation by molten phases and to the abrasion, the thermal shock resistance and the mechanical strength [5].Presently, the industry requires research on refractories with better properties that are manufactured using new technologies of agglomeration (faster, cheaper and cleaner) to improve their processes, for instance, studies of: new clean techniques of sintering (solar synthesis, laser, microwave and conventional sintering), synthesis of ceramic composites, incorporation of additives to improve properties of the refractories and study of nanomaterials added to the refractory matrix [6][7][8][9][...
The chemical environment and the internal conditions of the furnaces and ladles are extremely aggressive for the refractories, so metallurgical industries demand refractory linings with greater durability and resistance to avoid unforeseen stoppages and to reduce the changes of the furnace lining. Therefore, the current work aims to evaluate the impact of the additions of ZrO 2 -nanoparticles (1, 3, and 5 wt. %) in magnesia-based bricks. A comparative study of the physical and chemical properties in bricks obtained using two cold pressing techniques (uniaxial and isostatic pressing) and two sintering temperatures (1550 and 1650 • C) was carried out. The microstructure and crystalline phase characteristics obtained after the heat treatments and the slag corrosion test was studied using scanning electron microscopy/electron dispersive X-ray spectroscopy (SEM/EDX) and X-ray diffraction (XRD). The results reveal that the sample with 5 wt. % of ZrO 2 nanoparticles (obtained by cold isostatic pressing and sintering at 1650 • C) has the lowest porosity and greatest resistance to penetration of blast furnace slag.2 of 20 to the martensitic transformation of the steels [2]. Zirconia confers to the refractories the following properties: strength, toughness, and chemical resistance under severe conditions. On the other hand, magnesium oxide (MgO) is a basic refractory material characterized by its refractoriness (high melting point, around 2800 • C). This material also has a thermal conductivity of 48 W/m·K at room temperature and has a good resistance to corrosion in the presence of basic material. Magnesia refractories, which are manufactured by mixing magnesium oxide with other materials (carbon, spinel, chromite, etc.) to obtain bricks with different shapes, are used in the lining of both furnaces and ladles employed in the metallurgical industry (basic oxygen furnace (BOF), electric arc furnaces (EAF), argon-oxygen-decarburization (AOD), ladle metallurgical furnaces (LMF), cement kilns and furnaces for nonferrous materials [3]).The main consumer of magnesia-based refractory bricks is the metallurgical industry, and particularly the iron and steelmaking industry, where they are mainly used in the slag line of the LMF, in the EAF and in the BOF [4]. Other consumers of magnesia bricks (magnesia-chromite) are the submerged arc furnaces (SAF) used in the copper manufacturing process, because of the resistances to the chemical degradation by molten phases and to the abrasion, the thermal shock resistance and the mechanical strength [5].Presently, the industry requires research on refractories with better properties that are manufactured using new technologies of agglomeration (faster, cheaper and cleaner) to improve their processes, for instance, studies of: new clean techniques of sintering (solar synthesis, laser, microwave and conventional sintering), synthesis of ceramic composites, incorporation of additives to improve properties of the refractories and study of nanomaterials added to the refractory matrix [6][7][8][9][...
The emergence of metamaterials and their continued prosperity have built a powerful working platform for accurately manipulating the behavior of electromagnetic waves, providing sufficient possibility for the realization of metamaterial absorbers with outstanding performance. However, metamaterial absorbers composed of metallic materials typically possess many unfavorable factors, such as non‐adjustable absorption, easy oxidation, low‐melting, and expensive preparation costs. The selection of dielectric materials provides excellent alternatives due to their remarkable properties, thus dielectric‐based metamaterial absorbers (DBMAs) have attracted much attention. To promote breakthroughs in DBMAs and guide their future development, this work systematically and deeply reviews the recent research progress of DBMAs from four different but progressive aspects, including physical principles; classifications, material selections and tunable properties; preparation technologies; and functional applications. Five different types of theories and related physical mechanisms, such as Mie resonance, guided‐mode resonance, and Anapole resonance, are briefly outlined to explain DBMAs having near‐perfect absorption performance. Mainstream material selections, structure designs, and different types of tunable DBMAs are highlighted. Several widely utilized preparation methods for customizing DBMAs are given. Various practical applications of DBMAs in sensing, stealth technology, solar energy absorption, and electromagnetic interference suppression are reviewed. Finally, some key challenges and feasible solutions for DBMAs’ future development are provided.
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