2012
DOI: 10.1680/nme.12.00007
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Solar cell based on PEO, inorganic cations and ionic liquids

Abstract: Quasi-solid-state dye-sensitized solar cells (DSSCs) based on polyethylene oxide (PEO), I2 and inorganic iodides (LiI, KI, NaI, NH4I) and/or ionic liquids ([DMIm]I, [EMIm]I, [MPIm]I, [HMIm]I) were prepared and investigated at AM1·5/10 and AM1·5 illumination conditions. Results revealed highest energy-conversion efficiencies for the PEO + I2 + LiI + [EMIm]I (60 wt%) quasi-solid-state electrolyte of 5·9% and 3·6% at AM1·5/10 and AM1·5, respectively. Moreover, it was shown (within fluctuations of the solar cells’… Show more

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Cited by 2 publications
(3 citation statements)
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“…From the beginning of polymeric electrolyte application in DSSCs, synthetic polymers have been used extensively in pristine, mixed, and composite forms including nanocomposites of many inorganic additives. ,− Some of the most commonly used synthetic polymers for the preparation of electrolytes are poly­(ethylene oxide), ,, , poly­(propylene oxide), poly­(acrylonitrile), poly­(butyl acrylate), , poly­(methyl methacrylate), poly­(vinyl chloride), , poly­(vinyl pyrrolidinone), poly­(vinylidene fluoride), and poly­(vinylidene fluoride-hexafluoropropylene). However, as these polymers are synthetically manufactured and not ecofriendly, recently much attention has been given to the possible application of biopolymers in DSSCs. Among many biopolymers, polysaccharides like cellulose, carrageenan, ,− agarose, ,…”
Section: Polymer Electrolytesmentioning
confidence: 99%
“…From the beginning of polymeric electrolyte application in DSSCs, synthetic polymers have been used extensively in pristine, mixed, and composite forms including nanocomposites of many inorganic additives. ,− Some of the most commonly used synthetic polymers for the preparation of electrolytes are poly­(ethylene oxide), ,, , poly­(propylene oxide), poly­(acrylonitrile), poly­(butyl acrylate), , poly­(methyl methacrylate), poly­(vinyl chloride), , poly­(vinyl pyrrolidinone), poly­(vinylidene fluoride), and poly­(vinylidene fluoride-hexafluoropropylene). However, as these polymers are synthetically manufactured and not ecofriendly, recently much attention has been given to the possible application of biopolymers in DSSCs. Among many biopolymers, polysaccharides like cellulose, carrageenan, ,− agarose, ,…”
Section: Polymer Electrolytesmentioning
confidence: 99%
“…4 Imidazolium-based ionic liquids represent a widely studied class of these materials, and many papers within this themed issue cover recent fi ndings regarding this type of ionic liquid in the crossover between nanomaterials and energy. 3,5,6 In addition, this issue presents derivatives and alternatives for designing new ionic liquids suitable for nanomaterials and energy. 4,7 Perhaps the greatest advantage of using ionic liquids is the fl exibility in design afforded by the vast choice of ions.…”
mentioning
confidence: 99%
“…From an introduction and brief history of ionic liquids 4 to the latest applications of using ionic liquids to process nanomaterials for energy applications, 3,[5][6][7] the Ionic Liquids and Nanomaterials for Energy themed issue covers the role ionic liquids will play in emerging nanotechnology and energy areas and the cross-over between the two fi elds. The future of ionic liquids in the fi eld of nanomaterials for energy applications is promising and this special issue highlights some of the potential.…”
mentioning
confidence: 99%