Spatially selective patterning of zinc oxide (ZnO) thin film was achieved by inkjet printing of ZnO sol-gel precursor. Factors affecting inkjet printed patterns including ink formulation and process parameters were investigated and are discussed in this paper. The morphologies of inkjet printed ZnO patterns were affected by the 'coffee ring' effect, is depend on the evaporation rate, surface tension and ink droplet volume. This surface morphology would further influent the growth of ZnO nanorods while inkjet printed ZnO patterns were employed as seed layer. Crystalline ZnO nanorods were selectively grew on inkjet printed ZnO seed layer which diameters were affected by morphology of underlying printed patterns.
IntroductionZinc oxide (ZnO) as an n-type II-VI inorganic semiconducting material can be used for sensor (gas [1, 2], biomedical [3] etc.), electronic [4], optoelectronic [5], and photovoltaic [6] applications. ZnO nano-structures [7] such as nano-wire and nanorod can be prepared from solid precursor (e.g. pulse laser deposition [8], magnetron sputtering [9] etc.) or solution precursor (e.g. sol-gel [10], hydrothermal synthesis [11], electrochemical deposition [12] and microwave-assisted synthesis [13]). Preparation methods using solution precursor are attractive due to reasons including homogeneity, large area deposition, low cost, and lower energy consumption. For instance, zinc acetate [14], zinc chloride [15] and zinc nitrate [16] etc. can be used as the precursors for ZnO. Solution routes normally produce inferior materials quality as compared to deposition processes using solid precursors. One important advantage of solution precursors is capability to perform selective area patterning on different substrates using conventional patterning techniques such as micro-molding [17], interference lithography [18], and templated electrodeposition [19]. Patterning solution precursor at specific area allows arrays of devices such as transistor, sensor etc. to be realized at large scale and with low materials wastage. Some of the patterning techniques require multiple processing steps to achieve patterning. Of the patterning techniques involving solution precursors, inkjet printing (IJP) provides unique strengths in terms of drop-on-demand, design flexibility, and rapid-prototyping. IJP had been employed to pattern functional materials (e.g. polymeric, metallic, ceramic) [20] for fabrication of different devices such as solar cell [21], transistor [22], sensors [23] and so on. IJP can be either used as the sole patterning technique or combined with other techniques such as surface energy patterning and photo-lithography.