Sol-gel fabricated one-dimensional LiFePO<sub>4</sub> microstructures for carbon nanotube-based nanocomposite freestanding sheet as cathode material for Li ion batteries

In this study LiFePO4/C composite particles were synthesized using five different carbon sources via a one-step sol-gel method. La-doped LiFePO4 was also synthesized using the sol-gel method. The XRD pattern of LixLayFePO4 (x = 0.9~1.0, y = 0~0.1) after being calcined at 700 °C for 10 h indicates that as the doping ratio increased, the sample’s cell volume first increased then decreased, reaching a maximum value of 293.36 Å3 (x = 0.94, y = 0.06). The XRD patterns of Li0.92La0.08FePO4 after being calcined at different temperatures for 10 h indicate that with increasing calcination temperature, the (311) diffraction peak drifted toward a smaller diffraction angle. Similarly, the XRD patterns of Li0.92La0.08FePO4 after being calcined at 700 °C for different durations indicate that with increasing calcination times, the (311) diffraction peak drifted toward a larger diffraction angle. The infrared spectrum pattern of LixLayFePO4 (x = 0.9~1.0, y = 0~0.1) after being calcined at 700 °C for 10 h shows absorption peaks corresponding to the vibrations of the Li–O bond and PO43- group. An SEM analysis of LixLayFePO4 (x = 1, y = 0; x = 0.96, y = 0.04; x = 0.92, y = 0.08) after being calcined at 700 °C for 10 h indicates that the particles were irregular in shape and of uniform size. The hysteresis loops of Li0.92La0.08FePO4 after being calcined at 600 °C, 700 °C, or 800 °C for 10 h indicate that with increasing calcination temperature, the Ms gradually increased, while the Mr and Hc decreased, with minimum values of 0.08 emu/g and 58.21 Oe, respectively. The Mössbauer spectra of LixLayFePO4 (x = 1, y = 0; x = 0.96, y = 0.04; x = 0.92, y = 0.08) after being calcined at 700 °C for 10 h indicate that all samples contained Doublet(1) and Doublet(2) peaks, dominated by Fe2+ compounds. The proportions of Fe2+ were 85.5% (x = 1, y = 0), 89.9% (x = 0.96, y = 0.04), and 96.0% (x = 0.92, y = 0.08). The maximum IS and QS of Doublet(1) for the three samples were 1.224 mm/s and 2.956 mm/s, respectively.

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Sol-gel fabricated one-dimensional LiFePO₄ microstructures for carbon nanotube-based nanocomposite freestanding sheet as cathode material for Li ion batteries

Cited by 3 publications

References 20 publications

Enhancement of LiFePO4 cathodic material through incorporation of reduced graphene oxide via a simple two-step procedure

Enhancement of LiFePO4 cathodic material through incorporation of reduced graphene oxide via a simple two-step procedure

Enhancement of Lifepo4 Cathodic Material Through Incorporation of Reduced Graphene Oxide Via a Simple Two-Step Procedure

Molecular Crystal Structure Simulations and Structure-Magnetic Properties of LiFePO4 Composite Particles Optimized by La

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Sol-gel fabricated one-dimensional LiFePO4 microstructures for carbon nanotube-based nanocomposite freestanding sheet as cathode material for Li ion batteries

Cited by 3 publications

References 20 publications

Enhancement of LiFePO4 cathodic material through incorporation of reduced graphene oxide via a simple two-step procedure

Enhancement of LiFePO4 cathodic material through incorporation of reduced graphene oxide via a simple two-step procedure

Enhancement of Lifepo4 Cathodic Material Through Incorporation of Reduced Graphene Oxide Via a Simple Two-Step Procedure

Molecular Crystal Structure Simulations and Structure-Magnetic Properties of LiFePO4 Composite Particles Optimized by La

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Sol-gel fabricated one-dimensional LiFePO₄ microstructures for carbon nanotube-based nanocomposite freestanding sheet as cathode material for Li ion batteries