Abstract. In this study, we investigated the management of long-term
environmental pollution by organic pollutants such as organochlorine
pesticides. We set out to identify conditions that are conducive to reducing
pollution levels for these persistent molecules and then propose a conceptual
model of organochlorine fate in water. Our approach looked at spatio-temporal
changes in pollutant contents in surface water (SW) and groundwater (GW) on a
large scale, in order to decipher the respective roles of soil, geology,
hydrology and past treatment practices. The case of chlordecone (CLD) on the
island of Martinique (1100 km2) was selected given the sampling
campaigns carried out since 2007 over more than 150 sites. CLD, its
metabolite chlordecone-5b-hydro (5bCLD) and the metabolite-to-parent-compound
ratio were compared. As regards the spatial variability of water
contamination, our results showed that banana cropping areas explained the
location of contaminated SW and GW, whereas the combination of soil and
geology factors explained the main spatial variability in the 5bCLD∕CLD
ratio. For temporal variability, these conditions defined a high diversity of
situations in terms of the duration of pollution, highlighting two groups:
water draining old geological formations and ferralsols or vertisols vs.
recent geology and andosols. A conceptual leaching model provided some key
information to help interpret downward trends in CLD and 5bCLD observed in
water. Lastly, a conceptual model of organochlorine fate is proposed to
explain the diversity of the 5bCLD∕CLD ratio in water. Our conclusions
highlight the combined role of soil and groundwater residence time for
differentiating between conditions that are more conducive, or not, to the
disappearance of CLD from the environment. This paper presents a model that
provides an overall perception of organochlorine pesticide fate in the
environment.