Polymerized quantum spin chains (i.e. spin chains with a periodic modulation of the coupling constants) exhibit plateaux in their magnetization curves when subjected to homogeneous external magnetic fields. We argue that the strong-coupling limit yields a simple but general explanation for the appearance of plateaux as well as of the associated quantization condition on the magnetization. We then proceed to explicitly compute series for the plateau boundaries of trimerized and quadrumerized spin-1/2 chains. The picture is completed by a discussion how the universality classes associated to the transitions at the boundaries of magnetization plateaux arise in many cases from a first order strong-coupling effective Hamiltonian.PACS numbers: 75.10. Jm, 75.40.Cx, 75.45.+j, 75.60.Ej Quantum spin systems at low (or zero) temperatures can exhibit plateaux in their magnetization curves when subjected to strong external fields. Such phenomena in quasi-one-dimensional systems have recently been the subject of intense interest. In one dimension, there is an intriguing interplay between theoretical progress on a systematic understanding of the underlying mechanisms (see e.g. [1]) and an increasing number of experiments (see e.g. [2,3]) on materials which are believed to be predominantly one-dimensional.Here we study polymerized spin-S quantum spin chains in a magnetic field. Their Hamiltonian is given bywhere we assume periodicity of the coupling constants with period p, i.e.We will mostly concentrate on spin S = 1/2 and the antiferromagnetic regime J x ≥ 0. The zero-temperature magnetization process of the S = 1/2 polymerized chains (1) was studied in [4] using finite-size diagonalization and a perturbative bosonization analysis around the case of equal coupling constants J x = J (apart from this and the dimerized case, only some trimerized [5,6] and quadrumerized [7] cases seem to have been studied in the literature). Here we wish to complete the picture by discussing the 'strong-coupling' limit where at least one coupling constant is small with respect to the others, i.e. J x0 → 0. As is known e.g. from studies of spin-ladders [8,9], the magnetization process is easy to understand if some J x0 = 0. In this limit, the chain (1) decouples into clusters of p spins. These 'strongly coupled' clusters magnetize independently such that at zero temperature the magnetization M can only take finitely many values. For spin S they are subject to the quantization conditionwith a normalization such that the magnetization has saturation values M = ±1. This quantization condition was obtained (for S = 1/2) in [4] and is a special case of a more general condition written down in [9]. In particular the latter was also motivated by considering a limit in which the system decouples into clusters of finitely many spins. In fact, this counting argument is completely independent of the internal coupling inside the cluster of the p spins. The quantization condition (3) is therefore insensitive to details of the model. However, not only the tr...