Sodium /  V 6 O 13 Polymer Electrolyte Cells

Munshi, M. Z. A.; Gilmour, A. S.; Smyrl, William H.; Owens, Boone B.

doi:10.1149/1.2097050

Cited by 36 publications

(17 citation statements)

References 9 publications

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“…The reports about V 6 O 13 for emerging energy storage are rare. In 1989, Munshi reported the electrochemical performance of V 6 O 13 as cathode materials for sodium polymer electrolyte cells. Afterward, only few related studies were reported .…”

Section: Vanadium Oxidesmentioning

confidence: 99%

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Xiong

Meng

et al. 2020

Adv Funct Materials

314

212

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The emerging electrochemical energy storage systems beyond Li‐ion batteries, including Na/K/Mg/Ca/Zn/Al‐ion batteries, attract extensive interest as the development of Li‐ion batteries is seriously hindered by the scarce lithium resources. During the past years, large amounts of studies have focused on the investigation of various electrode materials toward emerging metal‐ion batteries to realize high energy density, high power density, and a long cycle life. In particular, vanadium‐based nanomaterials have received great attention. Vanadium‐based compounds have a big family with different structures, chemical compositions, and electrochemical properties, which provide huge possibilities for the development of emerging electrochemical energy storage. In this review, a comprehensive overview of the recent progresses of promising vanadium‐based nanomaterials for emerging metal‐ion batteries is presented. The vanadium‐based materials are classified into four groups: vanadium oxides, vanadates, vanadium phosphates, and oxygen‐free vanadium‐based compounds. The structures, electrochemical properties, and modification strategies are discussed. The structure–performance relationships and charge storage mechanisms are focused on. Finally, the perspectives about future directions of vanadium‐based nanomaterials for emerging energy storage devices are proposed. This review will provide comprehensive knowledge of vanadium‐based nanomaterials and shed light on their potential applications in emerging energy storage.

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Section: Vanadium Oxidesmentioning

confidence: 99%

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Xiong

Meng

et al. 2020

Adv Funct Materials

314

212

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“…electrophilic aromatic substitutions (Mouhtady et al, 2003) or cationic polymerizations (Sage et al, 2004). The highest activity is presently displayed in the context of high-energy batteries, particularly lithium-ion batteries, where alkali, zinc or magnesium trifluoromethyl sulfonates are contained in some of the complex (gel) polymer electrolytes (McLin & Angell, 1992;Munshi et al, 1989;Greenbaum, 1987;Semkow & Sammels, 1987;Forsyth et al, 1997;Zheng et al, 1998;Rhodes et al, 1999Rhodes et al, , 2002Ikeda, Mori, Furuhashi, Masuda & Yamamoto, 1999;Kumar & Munichandraiah, 2000a,b;Mitra et al, 2001;Kumar & Sampath, 2003). Our interest in trifluoromethyl sulfonates originates from the various degrees of rotational freedom available to the anion in the solid state.…”

Section: Introductionmentioning

confidence: 99%

Crystal structures of the trifluoromethyl sulfonates M(SO₃CF₃)₂ (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data

Dinnebiér

Sofina

Hildebrandt

et al. 2006

Acta Crystallogr Sect B

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The crystal structures of divalent metal salts of trifluoromethyl sulfonic acid ("trifluoromethyl sulfonates") M(SO(3)CF(3))(2) (M = Mg, Ca, Ba, Zn, Cu) were determined from high-resolution X-ray powder diffraction data. Magnesium, calcium and zinc trifluoromethyl sulfonate crystallize in the rhombohedral space group R(bar)3. Barium trifluoromethyl sulfonate crystallizes in the monoclinic space group I2/a(C2/c) and copper trifluoromethyl sulfonate crystallizes in the triclinic group P(bar)1. Within the crystal structures the trifluoromethyl sulfonate anions are arranged in double layers with the apolar CF(3) groups pointing towards each other. The cations are located next to the SO(3) groups. The symmetry relations between the different crystal structures have been analysed.

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“…Amita Chandra et al [14] studied a composite polymer electrolyte (PEO+NH4I+AI203) which should improve the film stability. Many rechargeable batteries have also been reported based on the Na § ion conducting polymers [15,16]. In the present paper, we report a new polymer electrolyte PEO+NaCIO3 system.…”

Section: Introductionmentioning

confidence: 79%

Ionic conductivity and battery characteristic studies on PEO+NaClO3 polymer electrolyte

Chandrasekaran

Mangani

Vasanthi

et al. 2001

Ionics

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Abstract. Solid polymer electrolyte films based on poly (ethylene oxide) PEO complcxed with NaCIO3 have been prepared by a solution-cast technique. The solvation of Na § ion with PEO is confirmed by XRD and IR studies. Measurements of the a.c. conductivity in the temperature range 308 -378 K and the transference numbers have been carried out to investigate the charge transport in this polymer electrolyte system. Transport number data show that the charge transport in this polymer electrolyte system is predominantly due to ions. The highest conductivity (2.12.10 .4 S/cm) has been observed for the 70:30 composition. Using the polymer electrolyte solid state electrochemical ceils have been fabricated. The various cell parameters are evaluated and reported.

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Sodium / V 6 O 13 Polymer Electrolyte Cells

Abstract: not Available.

Cited by 36 publications

References 9 publications

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Crystal structures of the trifluoromethyl sulfonates M(SO₃CF₃)₂ (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data

Ionic conductivity and battery characteristic studies on PEO+NaClO3 polymer electrolyte

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Sodium / V 6 O 13 Polymer Electrolyte Cells

Abstract: not Available.

Cited by 36 publications

References 9 publications

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries

Crystal structures of the trifluoromethyl sulfonates M(SO3CF3)2 (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data

Ionic conductivity and battery characteristic studies on PEO+NaClO3 polymer electrolyte

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Crystal structures of the trifluoromethyl sulfonates M(SO₃CF₃)₂ (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data