2009
DOI: 10.1103/physrevb.79.115101
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Sodium ion and cobalt charge ordering inNaxCoO2(x56

Abstract: We present a direct study of the Co charge order and Na ordering in three Co-layers Na x CoO 2 ͑x ϳ 5 6 ͒ single crystals. From diffuse scattering measurements, we propose a model of Na supercell which rules out the ones previously suggested in parent cobaltates with double Co layers. Via a direct measurement of the Co charge state using anomalous x-ray scattering, we also evidence a Co charge order which evolves between 200 and 290 K.

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Cited by 11 publications
(11 citation statements)
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References 30 publications
(45 reference statements)
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“…It would be interesting to explore more the interplay between structural disorder, CDW and superconductivity in tungsten oxides. Indeed, doping of WO3 leads to the superconductivity below ~ 4 K [36] or CDW state at TCDW ~ 150 K [37]. Results reported in Refs.…”
Section: E Tungsten Oxidesmentioning
confidence: 78%
“…It would be interesting to explore more the interplay between structural disorder, CDW and superconductivity in tungsten oxides. Indeed, doping of WO3 leads to the superconductivity below ~ 4 K [36] or CDW state at TCDW ~ 150 K [37]. Results reported in Refs.…”
Section: E Tungsten Oxidesmentioning
confidence: 78%
“…Thus, both the charge as well as Na ordering have crucial role on the magnetic and electrical properties of the Na x CoO 2 oxides. A pronounced effect of Na ordering on the transport properties is indeed observed for higher sodium contents 7477. Theoretical calculations reveal the role of Na potential on magnetic correlations 78.…”
Section: Layered Cobaltates: Naxcoo2mentioning
confidence: 78%
“… Temperature dependence of the resistivity of Na 5/6 CoO 2 measured in the (ab) plane upon cooling (blue curve) and upon heating (red curve) 77…”
Section: Layered Cobaltates: Naxcoo2mentioning
confidence: 99%
“…This technique has been essential in a number of high-profile cases, as for example the orbital and charge ordering in transition metals [94][95][96][97][98][99][100][101], frustrated magnetism in low dimensional magnetic systems [102,103], multiferroics [104,105], heavy fermion antiferromagnets [106,107], picnide superconductors [108][109][110], magnetic thin films and multilayers [111,112].…”
Section: Discussionmentioning
confidence: 99%