Studies indicated that individuals who tend to smile while taking their photographs tend to experience more positive emotions in their life and, in turn, achieve superior outcomes in several life domains. However, little is known whether positive emotionality revealed in players' profile photographs is related to sports performance. This study examined whether the smiling intensity in volleyball players' profiles (full, partial, and no smile) predicted individual (e.g., points scored, service, and reception errors) and team performance (winning a match). Building upon previous studies on positive emotions, we expected that players presenting full (Duchenne) smiles would achieve better results. We analyzed 196 volleyball players' profiles from the Polish highest-level professional league competition (PlusLiga). Raters coded smile intensity. Using three-level path models, we found that teams with more frequent Duchenne smiles performed as well as those who presented Duchenne smiles less often. We conclude that positive emotionality (as reflected in profile photo smiling) might be independent of male volleyball accomplishments.